In-situ nanospectroscopic imaging of plasmon-induced two-dimensional [4+4]-cycloaddition polymerization on Au(111)

Here, the authors use tip-enhanced Raman spectroscopy for in-situ investigation of plasmon-induced [4+4]-cycloaddition polymerization on Au(111). They find that this occurs by a hot electron tunneling mechanism, while crosslinks form via a self-stimulating growth mechanism.

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Autores principales: Feng Shao, Wei Wang, Weimin Yang, Zhilin Yang, Yao Zhang, Jinggang Lan, A. Dieter Schlüter, Renato Zenobi
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/85bba13a311b4c668dad579baf47f5bb
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spelling oai:doaj.org-article:85bba13a311b4c668dad579baf47f5bb2021-12-02T18:47:04ZIn-situ nanospectroscopic imaging of plasmon-induced two-dimensional [4+4]-cycloaddition polymerization on Au(111)10.1038/s41467-021-24856-52041-1723https://doaj.org/article/85bba13a311b4c668dad579baf47f5bb2021-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-24856-5https://doaj.org/toc/2041-1723Here, the authors use tip-enhanced Raman spectroscopy for in-situ investigation of plasmon-induced [4+4]-cycloaddition polymerization on Au(111). They find that this occurs by a hot electron tunneling mechanism, while crosslinks form via a self-stimulating growth mechanism.Feng ShaoWei WangWeimin YangZhilin YangYao ZhangJinggang LanA. Dieter SchlüterRenato ZenobiNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-10 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Feng Shao
Wei Wang
Weimin Yang
Zhilin Yang
Yao Zhang
Jinggang Lan
A. Dieter Schlüter
Renato Zenobi
In-situ nanospectroscopic imaging of plasmon-induced two-dimensional [4+4]-cycloaddition polymerization on Au(111)
description Here, the authors use tip-enhanced Raman spectroscopy for in-situ investigation of plasmon-induced [4+4]-cycloaddition polymerization on Au(111). They find that this occurs by a hot electron tunneling mechanism, while crosslinks form via a self-stimulating growth mechanism.
format article
author Feng Shao
Wei Wang
Weimin Yang
Zhilin Yang
Yao Zhang
Jinggang Lan
A. Dieter Schlüter
Renato Zenobi
author_facet Feng Shao
Wei Wang
Weimin Yang
Zhilin Yang
Yao Zhang
Jinggang Lan
A. Dieter Schlüter
Renato Zenobi
author_sort Feng Shao
title In-situ nanospectroscopic imaging of plasmon-induced two-dimensional [4+4]-cycloaddition polymerization on Au(111)
title_short In-situ nanospectroscopic imaging of plasmon-induced two-dimensional [4+4]-cycloaddition polymerization on Au(111)
title_full In-situ nanospectroscopic imaging of plasmon-induced two-dimensional [4+4]-cycloaddition polymerization on Au(111)
title_fullStr In-situ nanospectroscopic imaging of plasmon-induced two-dimensional [4+4]-cycloaddition polymerization on Au(111)
title_full_unstemmed In-situ nanospectroscopic imaging of plasmon-induced two-dimensional [4+4]-cycloaddition polymerization on Au(111)
title_sort in-situ nanospectroscopic imaging of plasmon-induced two-dimensional [4+4]-cycloaddition polymerization on au(111)
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/85bba13a311b4c668dad579baf47f5bb
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