Thermodynamically stable whilst kinetically labile coordination bonds lead to strong and tough self-healing polymers

There is often a trade-off between mechanical properties (modulus and toughness) and dynamic self-healing in materials. Here the authors design and synthesize a polymer containing thermodynamically stable whilst kinetically labile coordination complexes to address this conundrum.

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Autores principales: Jian-Cheng Lai, Xiao-Yong Jia, Da-Peng Wang, Yi-Bing Deng, Peng Zheng, Cheng-Hui Li, Jing-Lin Zuo, Zhenan Bao
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/85c07b65ac5a419487cdf20dfd379ad2
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spelling oai:doaj.org-article:85c07b65ac5a419487cdf20dfd379ad22021-12-02T15:35:40ZThermodynamically stable whilst kinetically labile coordination bonds lead to strong and tough self-healing polymers10.1038/s41467-019-09130-z2041-1723https://doaj.org/article/85c07b65ac5a419487cdf20dfd379ad22019-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-09130-zhttps://doaj.org/toc/2041-1723There is often a trade-off between mechanical properties (modulus and toughness) and dynamic self-healing in materials. Here the authors design and synthesize a polymer containing thermodynamically stable whilst kinetically labile coordination complexes to address this conundrum.Jian-Cheng LaiXiao-Yong JiaDa-Peng WangYi-Bing DengPeng ZhengCheng-Hui LiJing-Lin ZuoZhenan BaoNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Jian-Cheng Lai
Xiao-Yong Jia
Da-Peng Wang
Yi-Bing Deng
Peng Zheng
Cheng-Hui Li
Jing-Lin Zuo
Zhenan Bao
Thermodynamically stable whilst kinetically labile coordination bonds lead to strong and tough self-healing polymers
description There is often a trade-off between mechanical properties (modulus and toughness) and dynamic self-healing in materials. Here the authors design and synthesize a polymer containing thermodynamically stable whilst kinetically labile coordination complexes to address this conundrum.
format article
author Jian-Cheng Lai
Xiao-Yong Jia
Da-Peng Wang
Yi-Bing Deng
Peng Zheng
Cheng-Hui Li
Jing-Lin Zuo
Zhenan Bao
author_facet Jian-Cheng Lai
Xiao-Yong Jia
Da-Peng Wang
Yi-Bing Deng
Peng Zheng
Cheng-Hui Li
Jing-Lin Zuo
Zhenan Bao
author_sort Jian-Cheng Lai
title Thermodynamically stable whilst kinetically labile coordination bonds lead to strong and tough self-healing polymers
title_short Thermodynamically stable whilst kinetically labile coordination bonds lead to strong and tough self-healing polymers
title_full Thermodynamically stable whilst kinetically labile coordination bonds lead to strong and tough self-healing polymers
title_fullStr Thermodynamically stable whilst kinetically labile coordination bonds lead to strong and tough self-healing polymers
title_full_unstemmed Thermodynamically stable whilst kinetically labile coordination bonds lead to strong and tough self-healing polymers
title_sort thermodynamically stable whilst kinetically labile coordination bonds lead to strong and tough self-healing polymers
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/85c07b65ac5a419487cdf20dfd379ad2
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AT xiaoyongjia thermodynamicallystablewhilstkineticallylabilecoordinationbondsleadtostrongandtoughselfhealingpolymers
AT dapengwang thermodynamicallystablewhilstkineticallylabilecoordinationbondsleadtostrongandtoughselfhealingpolymers
AT yibingdeng thermodynamicallystablewhilstkineticallylabilecoordinationbondsleadtostrongandtoughselfhealingpolymers
AT pengzheng thermodynamicallystablewhilstkineticallylabilecoordinationbondsleadtostrongandtoughselfhealingpolymers
AT chenghuili thermodynamicallystablewhilstkineticallylabilecoordinationbondsleadtostrongandtoughselfhealingpolymers
AT jinglinzuo thermodynamicallystablewhilstkineticallylabilecoordinationbondsleadtostrongandtoughselfhealingpolymers
AT zhenanbao thermodynamicallystablewhilstkineticallylabilecoordinationbondsleadtostrongandtoughselfhealingpolymers
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