Time-Resolved Nanobeam X-ray Diffraction of a Relaxor Ferroelectric Single Crystal under an Alternating Electric Field

Lead-containing relaxor ferroelectrics show enormous piezoelectric capabilities relating to their heterogeneous structures. Time-resolved nanobeam X-ray diffraction reveals the time and position dependences of the local lattice strain on a relaxor ferroelectric single crystal mechanically vibrating...

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Autores principales: Shinobu Aoyagi, Ayumi Aoyagi, Hiroaki Takeda, Hitoshi Osawa, Kazushi Sumitani, Yasuhiko Imai, Shigeru Kimura
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Lenguaje:EN
Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/8651f105624c49248f406882464c6837
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spelling oai:doaj.org-article:8651f105624c49248f406882464c68372021-11-25T17:19:37ZTime-Resolved Nanobeam X-ray Diffraction of a Relaxor Ferroelectric Single Crystal under an Alternating Electric Field10.3390/cryst111114192073-4352https://doaj.org/article/8651f105624c49248f406882464c68372021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4352/11/11/1419https://doaj.org/toc/2073-4352Lead-containing relaxor ferroelectrics show enormous piezoelectric capabilities relating to their heterogeneous structures. Time-resolved nanobeam X-ray diffraction reveals the time and position dependences of the local lattice strain on a relaxor ferroelectric single crystal mechanically vibrating and alternately switching, as well as its polarization under an alternating electric field. The complicated time and position dependences of the Bragg intensity distributions under an alternating electric field demonstrate that nanodomains with the various lattice constants and orientations exhibiting different electric field responses exist in the measured local area, as the translation symmetry breaks to the microscale. The dynamic motion of nanodomains in the heterogeneous structure, with widely distributed local lattice strain, enables enormous piezoelectric lattice strain and fatigue-free ferroelectric polarization switching.Shinobu AoyagiAyumi AoyagiHiroaki TakedaHitoshi OsawaKazushi SumitaniYasuhiko ImaiShigeru KimuraMDPI AGarticlesynchrotron radiationnanobeam X-ray diffractiontime-resolved X-ray diffractionrelaxor ferroelectricsCrystallographyQD901-999ENCrystals, Vol 11, Iss 1419, p 1419 (2021)
institution DOAJ
collection DOAJ
language EN
topic synchrotron radiation
nanobeam X-ray diffraction
time-resolved X-ray diffraction
relaxor ferroelectrics
Crystallography
QD901-999
spellingShingle synchrotron radiation
nanobeam X-ray diffraction
time-resolved X-ray diffraction
relaxor ferroelectrics
Crystallography
QD901-999
Shinobu Aoyagi
Ayumi Aoyagi
Hiroaki Takeda
Hitoshi Osawa
Kazushi Sumitani
Yasuhiko Imai
Shigeru Kimura
Time-Resolved Nanobeam X-ray Diffraction of a Relaxor Ferroelectric Single Crystal under an Alternating Electric Field
description Lead-containing relaxor ferroelectrics show enormous piezoelectric capabilities relating to their heterogeneous structures. Time-resolved nanobeam X-ray diffraction reveals the time and position dependences of the local lattice strain on a relaxor ferroelectric single crystal mechanically vibrating and alternately switching, as well as its polarization under an alternating electric field. The complicated time and position dependences of the Bragg intensity distributions under an alternating electric field demonstrate that nanodomains with the various lattice constants and orientations exhibiting different electric field responses exist in the measured local area, as the translation symmetry breaks to the microscale. The dynamic motion of nanodomains in the heterogeneous structure, with widely distributed local lattice strain, enables enormous piezoelectric lattice strain and fatigue-free ferroelectric polarization switching.
format article
author Shinobu Aoyagi
Ayumi Aoyagi
Hiroaki Takeda
Hitoshi Osawa
Kazushi Sumitani
Yasuhiko Imai
Shigeru Kimura
author_facet Shinobu Aoyagi
Ayumi Aoyagi
Hiroaki Takeda
Hitoshi Osawa
Kazushi Sumitani
Yasuhiko Imai
Shigeru Kimura
author_sort Shinobu Aoyagi
title Time-Resolved Nanobeam X-ray Diffraction of a Relaxor Ferroelectric Single Crystal under an Alternating Electric Field
title_short Time-Resolved Nanobeam X-ray Diffraction of a Relaxor Ferroelectric Single Crystal under an Alternating Electric Field
title_full Time-Resolved Nanobeam X-ray Diffraction of a Relaxor Ferroelectric Single Crystal under an Alternating Electric Field
title_fullStr Time-Resolved Nanobeam X-ray Diffraction of a Relaxor Ferroelectric Single Crystal under an Alternating Electric Field
title_full_unstemmed Time-Resolved Nanobeam X-ray Diffraction of a Relaxor Ferroelectric Single Crystal under an Alternating Electric Field
title_sort time-resolved nanobeam x-ray diffraction of a relaxor ferroelectric single crystal under an alternating electric field
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/8651f105624c49248f406882464c6837
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AT ayumiaoyagi timeresolvednanobeamxraydiffractionofarelaxorferroelectricsinglecrystalunderanalternatingelectricfield
AT hiroakitakeda timeresolvednanobeamxraydiffractionofarelaxorferroelectricsinglecrystalunderanalternatingelectricfield
AT hitoshiosawa timeresolvednanobeamxraydiffractionofarelaxorferroelectricsinglecrystalunderanalternatingelectricfield
AT kazushisumitani timeresolvednanobeamxraydiffractionofarelaxorferroelectricsinglecrystalunderanalternatingelectricfield
AT yasuhikoimai timeresolvednanobeamxraydiffractionofarelaxorferroelectricsinglecrystalunderanalternatingelectricfield
AT shigerukimura timeresolvednanobeamxraydiffractionofarelaxorferroelectricsinglecrystalunderanalternatingelectricfield
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