The key role of Au-substrate interactions in catalytic gold subnanoclusters

Stabilization of gold nanoclusters in order to prevent their self-aggregation remains a great challenge. Here, the authors describe transient stabilization of very small catalytic gold subnanoclusters by alkyl chains or aromatic groups appended to the reactive π bond of simple alkynes.

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Detalles Bibliográficos
Autores principales: Jesús Cordón, Gonzalo Jiménez-Osés, José M. López-de-Luzuriaga, Miguel Monge
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/866f30c4e7514bd59d928a7a5565eac8
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Sumario:Stabilization of gold nanoclusters in order to prevent their self-aggregation remains a great challenge. Here, the authors describe transient stabilization of very small catalytic gold subnanoclusters by alkyl chains or aromatic groups appended to the reactive π bond of simple alkynes.