The Synergetic Effect Induced High Electrochemical Performance of CuO/Cu2O/Cu Nanocomposites as Lithium-Ion Battery Anodes

Due to the high theoretical capability, copper-based oxides were widely investigated. A facile water bath method was used to synthesis CuO nanowires and CuO/Cu2O/Cu nanocomposites. Owing to the synergetic effect, the CuO/Cu2O/Cu nanocomposites exhibit superior electrochemical performance compared to...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Lin-Hui Wang, Shang Gao, Long-Long Ren, En-Long Zhou, Yu-Feng Qin
Formato:	article
Lenguaje:	EN
Publicado:	Frontiers Media S.A. 2021
Materias:	CuO/Cu2O/Cu nanocomposites CuO nanowires lithium-ion batteries anodes water bath method electrochemical performance Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/872d47715a804bc5919e59d33778da0a
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:872d47715a804bc5919e59d33778da0a
record_format	dspace
spelling	oai:doaj.org-article:872d47715a804bc5919e59d33778da0a2021-11-22T04:41:11ZThe Synergetic Effect Induced High Electrochemical Performance of CuO/Cu2O/Cu Nanocomposites as Lithium-Ion Battery Anodes2296-264610.3389/fchem.2021.790659https://doaj.org/article/872d47715a804bc5919e59d33778da0a2021-11-01T00:00:00Zhttps://www.frontiersin.org/articles/10.3389/fchem.2021.790659/fullhttps://doaj.org/toc/2296-2646Due to the high theoretical capability, copper-based oxides were widely investigated. A facile water bath method was used to synthesis CuO nanowires and CuO/Cu2O/Cu nanocomposites. Owing to the synergetic effect, the CuO/Cu2O/Cu nanocomposites exhibit superior electrochemical performance compared to the CuO nanowires. The initial discharge and charge capacities are 2,660.4 mAh/g and 2,107.8 mAh/g, and the reversible capacity is 1,265.7 mAh/g after 200 cycles at 200 mA/g. Moreover, the reversible capacity is 1,180 mAh/g at 800 mA/g and 1,750 mAh/g when back to 100 mA/g, indicating the excellent rate capability. The CuO/Cu2O/Cu nanocomposites also exhibit relatively high electric conductivity and lithium-ion diffusion coefficient, especially after cycling. For the energy storage mechanism, the capacitive controlled mechanism is predominance at the high scan rates, which is consistent with the excellent rate capability. The outstanding electrochemical performance of the CuO/Cu2O/Cu nanocomposites indicates the potential application of copper-based oxides nanomaterials in future lithium-ion batteries.Lin-Hui WangShang GaoLong-Long RenEn-Long ZhouYu-Feng QinFrontiers Media S.A.articleCuO/Cu2O/Cu nanocompositesCuO nanowireslithium-ion batteriesanodeswater bath methodelectrochemical performanceChemistryQD1-999ENFrontiers in Chemistry, Vol 9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	CuO/Cu2O/Cu nanocomposites CuO nanowires lithium-ion batteries anodes water bath method electrochemical performance Chemistry QD1-999
spellingShingle	CuO/Cu2O/Cu nanocomposites CuO nanowires lithium-ion batteries anodes water bath method electrochemical performance Chemistry QD1-999 Lin-Hui Wang Shang Gao Long-Long Ren En-Long Zhou Yu-Feng Qin The Synergetic Effect Induced High Electrochemical Performance of CuO/Cu2O/Cu Nanocomposites as Lithium-Ion Battery Anodes
description	Due to the high theoretical capability, copper-based oxides were widely investigated. A facile water bath method was used to synthesis CuO nanowires and CuO/Cu2O/Cu nanocomposites. Owing to the synergetic effect, the CuO/Cu2O/Cu nanocomposites exhibit superior electrochemical performance compared to the CuO nanowires. The initial discharge and charge capacities are 2,660.4 mAh/g and 2,107.8 mAh/g, and the reversible capacity is 1,265.7 mAh/g after 200 cycles at 200 mA/g. Moreover, the reversible capacity is 1,180 mAh/g at 800 mA/g and 1,750 mAh/g when back to 100 mA/g, indicating the excellent rate capability. The CuO/Cu2O/Cu nanocomposites also exhibit relatively high electric conductivity and lithium-ion diffusion coefficient, especially after cycling. For the energy storage mechanism, the capacitive controlled mechanism is predominance at the high scan rates, which is consistent with the excellent rate capability. The outstanding electrochemical performance of the CuO/Cu2O/Cu nanocomposites indicates the potential application of copper-based oxides nanomaterials in future lithium-ion batteries.
format	article
author	Lin-Hui Wang Shang Gao Long-Long Ren En-Long Zhou Yu-Feng Qin
author_facet	Lin-Hui Wang Shang Gao Long-Long Ren En-Long Zhou Yu-Feng Qin
author_sort	Lin-Hui Wang
title	The Synergetic Effect Induced High Electrochemical Performance of CuO/Cu2O/Cu Nanocomposites as Lithium-Ion Battery Anodes
title_short	The Synergetic Effect Induced High Electrochemical Performance of CuO/Cu2O/Cu Nanocomposites as Lithium-Ion Battery Anodes
title_full	The Synergetic Effect Induced High Electrochemical Performance of CuO/Cu2O/Cu Nanocomposites as Lithium-Ion Battery Anodes
title_fullStr	The Synergetic Effect Induced High Electrochemical Performance of CuO/Cu2O/Cu Nanocomposites as Lithium-Ion Battery Anodes
title_full_unstemmed	The Synergetic Effect Induced High Electrochemical Performance of CuO/Cu2O/Cu Nanocomposites as Lithium-Ion Battery Anodes
title_sort	synergetic effect induced high electrochemical performance of cuo/cu2o/cu nanocomposites as lithium-ion battery anodes
publisher	Frontiers Media S.A.
publishDate	2021
url	https://doaj.org/article/872d47715a804bc5919e59d33778da0a
work_keys_str_mv	AT linhuiwang thesynergeticeffectinducedhighelectrochemicalperformanceofcuocu2ocunanocompositesaslithiumionbatteryanodes AT shanggao thesynergeticeffectinducedhighelectrochemicalperformanceofcuocu2ocunanocompositesaslithiumionbatteryanodes AT longlongren thesynergeticeffectinducedhighelectrochemicalperformanceofcuocu2ocunanocompositesaslithiumionbatteryanodes AT enlongzhou thesynergeticeffectinducedhighelectrochemicalperformanceofcuocu2ocunanocompositesaslithiumionbatteryanodes AT yufengqin thesynergeticeffectinducedhighelectrochemicalperformanceofcuocu2ocunanocompositesaslithiumionbatteryanodes AT linhuiwang synergeticeffectinducedhighelectrochemicalperformanceofcuocu2ocunanocompositesaslithiumionbatteryanodes AT shanggao synergeticeffectinducedhighelectrochemicalperformanceofcuocu2ocunanocompositesaslithiumionbatteryanodes AT longlongren synergeticeffectinducedhighelectrochemicalperformanceofcuocu2ocunanocompositesaslithiumionbatteryanodes AT enlongzhou synergeticeffectinducedhighelectrochemicalperformanceofcuocu2ocunanocompositesaslithiumionbatteryanodes AT yufengqin synergeticeffectinducedhighelectrochemicalperformanceofcuocu2ocunanocompositesaslithiumionbatteryanodes
_version_	1718418172936192000

The Synergetic Effect Induced High Electrochemical Performance of CuO/Cu2O/Cu Nanocomposites as Lithium-Ion Battery Anodes

Ejemplares similares