CO2 introduced the coagulation-flocculation of oil acidized wastewater: pollutant removal and cost analysis

It is difficult to adjust the pH of oil acidized wastewater rich in Ca2+, thus hindering the polyacrylamide (PAM) flocculation. This study aims at accelerating the flocculation process by introducing CO2 into the water to induce the formation of CaCO3 nuclei. The order in which CO2 and NaOH were add...

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Autores principales: Jinyi Qin, Yifan Gong, Chuan Qin, Hailong Meng, Yiwen He, Qingyang Qin, Junfa Gao
Formato: article
Lenguaje:EN
Publicado: IWA Publishing 2021
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co2
Acceso en línea:https://doaj.org/article/873a79a021894db698aad856ae31a78d
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spelling oai:doaj.org-article:873a79a021894db698aad856ae31a78d2021-11-06T10:50:51ZCO2 introduced the coagulation-flocculation of oil acidized wastewater: pollutant removal and cost analysis0273-12231996-973210.2166/wst.2021.054https://doaj.org/article/873a79a021894db698aad856ae31a78d2021-03-01T00:00:00Zhttp://wst.iwaponline.com/content/83/5/1108https://doaj.org/toc/0273-1223https://doaj.org/toc/1996-9732It is difficult to adjust the pH of oil acidized wastewater rich in Ca2+, thus hindering the polyacrylamide (PAM) flocculation. This study aims at accelerating the flocculation process by introducing CO2 into the water to induce the formation of CaCO3 nuclei. The order in which CO2 and NaOH were added affected the floc structures. Compared with CO2-NaOH-PAM, the flocs of NaOH-CO2-PAM were more compact and more CaCO3 crystals were formed. The aqueous Ca2+ involved in the reaction reached 20%, and CO2 utilization was enhanced. The settling time was shortened by half (from 20 to 3 min), and NaOH consumption was reduced by one-tenth (from 0.03 to 0.003 mol), hence significantly reducing the costs. Due to the higher settling rate and shorter contact time, the NaOH-CO2-PAM flocs adsorbed less so that the residual oil was 124 mg·L−1, while in the case of CO2-NaOH-PAM it was 88 mg·L−1. As a promising coagulation aid, CO2 can also be used to mineralize pollutants in wastewater.Jinyi QinYifan GongChuan QinHailong MengYiwen HeQingyang QinJunfa GaoIWA Publishingarticleca2+co2floc coreoil acidized wastewaterpolyacrylamideEnvironmental technology. Sanitary engineeringTD1-1066ENWater Science and Technology, Vol 83, Iss 5, Pp 1108-1117 (2021)
institution DOAJ
collection DOAJ
language EN
topic ca2+
co2
floc core
oil acidized wastewater
polyacrylamide
Environmental technology. Sanitary engineering
TD1-1066
spellingShingle ca2+
co2
floc core
oil acidized wastewater
polyacrylamide
Environmental technology. Sanitary engineering
TD1-1066
Jinyi Qin
Yifan Gong
Chuan Qin
Hailong Meng
Yiwen He
Qingyang Qin
Junfa Gao
CO2 introduced the coagulation-flocculation of oil acidized wastewater: pollutant removal and cost analysis
description It is difficult to adjust the pH of oil acidized wastewater rich in Ca2+, thus hindering the polyacrylamide (PAM) flocculation. This study aims at accelerating the flocculation process by introducing CO2 into the water to induce the formation of CaCO3 nuclei. The order in which CO2 and NaOH were added affected the floc structures. Compared with CO2-NaOH-PAM, the flocs of NaOH-CO2-PAM were more compact and more CaCO3 crystals were formed. The aqueous Ca2+ involved in the reaction reached 20%, and CO2 utilization was enhanced. The settling time was shortened by half (from 20 to 3 min), and NaOH consumption was reduced by one-tenth (from 0.03 to 0.003 mol), hence significantly reducing the costs. Due to the higher settling rate and shorter contact time, the NaOH-CO2-PAM flocs adsorbed less so that the residual oil was 124 mg·L−1, while in the case of CO2-NaOH-PAM it was 88 mg·L−1. As a promising coagulation aid, CO2 can also be used to mineralize pollutants in wastewater.
format article
author Jinyi Qin
Yifan Gong
Chuan Qin
Hailong Meng
Yiwen He
Qingyang Qin
Junfa Gao
author_facet Jinyi Qin
Yifan Gong
Chuan Qin
Hailong Meng
Yiwen He
Qingyang Qin
Junfa Gao
author_sort Jinyi Qin
title CO2 introduced the coagulation-flocculation of oil acidized wastewater: pollutant removal and cost analysis
title_short CO2 introduced the coagulation-flocculation of oil acidized wastewater: pollutant removal and cost analysis
title_full CO2 introduced the coagulation-flocculation of oil acidized wastewater: pollutant removal and cost analysis
title_fullStr CO2 introduced the coagulation-flocculation of oil acidized wastewater: pollutant removal and cost analysis
title_full_unstemmed CO2 introduced the coagulation-flocculation of oil acidized wastewater: pollutant removal and cost analysis
title_sort co2 introduced the coagulation-flocculation of oil acidized wastewater: pollutant removal and cost analysis
publisher IWA Publishing
publishDate 2021
url https://doaj.org/article/873a79a021894db698aad856ae31a78d
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AT yiwenhe co2introducedthecoagulationflocculationofoilacidizedwastewaterpollutantremovalandcostanalysis
AT qingyangqin co2introducedthecoagulationflocculationofoilacidizedwastewaterpollutantremovalandcostanalysis
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