Potential low-cost carbon-based adsorbent from gold mine tailings for anionic dye removal
In this study, a mesoporous carbon (CMK-3) was successfully synthesized using mesoporous silica (SBA-15) prepared from gold mine tailings (sample CGMT) for removal of anionic dye from aqueous solution. For comparison, CMK-3 was prepared by the same method from pure silica (sample CT), and the other...
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Formato: | article |
Lenguaje: | EN |
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IWA Publishing
2021
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Materias: | |
Acceso en línea: | https://doaj.org/article/874dd414fb7c42c58ebc64d7862b0891 |
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Sumario: | In this study, a mesoporous carbon (CMK-3) was successfully synthesized using mesoporous silica (SBA-15) prepared from gold mine tailings (sample CGMT) for removal of anionic dye from aqueous solution. For comparison, CMK-3 was prepared by the same method from pure silica (sample CT), and the other CMK-3 sample was prepared by a one-pot route mixing with Pluronic P123 (sample CP). The effect of the carbonization time on the synthesis of all CMK-3 samples was investigated, and the samples were characterized by X-ray diffraction and N2 adsorption–desorption. The sample with the highest surface area was chosen as an adsorbent, for each CMK-3 obtained from different methods. Batch adsorption experiments were studied to determine the influence of pH, contact time, and initial dye concentration. The adsorption kinetics obeyed the pseudo-second-order model. All carbon-based adsorbents were observed to be quite effective for the removal of dye with adsorption percentage in the order of CP > CT > CGMT. The maximum adsorption capacities were 188.99 and 204.57 mg·g−1 for CT and CGMT, respectively. The comparative results of all carbon-based adsorbents show that CGMT can be applied as a low-cost alternative to CT for dye removal. HIGHLIGHTS
CMK-3 was synthesized from gold mine waste (CGMT) for the first time.;
The usage of CGMT as low-cost adsorbent for the removal of dye was investigated.;
For comparison, other adsorbents synthesized from different methods were investigated as an adsorbent in the dye adsorption.;
The specific surface area, pore volume and pore size dominate the adsorption capacity.;
CGMT can be applied as a novel, low-cost and alternative adsorbent for dye removal.; |
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