Potential low-cost carbon-based adsorbent from gold mine tailings for anionic dye removal
In this study, a mesoporous carbon (CMK-3) was successfully synthesized using mesoporous silica (SBA-15) prepared from gold mine tailings (sample CGMT) for removal of anionic dye from aqueous solution. For comparison, CMK-3 was prepared by the same method from pure silica (sample CT), and the other...
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2021
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oai:doaj.org-article:874dd414fb7c42c58ebc64d7862b08912021-11-06T10:52:21ZPotential low-cost carbon-based adsorbent from gold mine tailings for anionic dye removal0273-12231996-973210.2166/wst.2021.052https://doaj.org/article/874dd414fb7c42c58ebc64d7862b08912021-03-01T00:00:00Zhttp://wst.iwaponline.com/content/83/6/1300https://doaj.org/toc/0273-1223https://doaj.org/toc/1996-9732In this study, a mesoporous carbon (CMK-3) was successfully synthesized using mesoporous silica (SBA-15) prepared from gold mine tailings (sample CGMT) for removal of anionic dye from aqueous solution. For comparison, CMK-3 was prepared by the same method from pure silica (sample CT), and the other CMK-3 sample was prepared by a one-pot route mixing with Pluronic P123 (sample CP). The effect of the carbonization time on the synthesis of all CMK-3 samples was investigated, and the samples were characterized by X-ray diffraction and N2 adsorption–desorption. The sample with the highest surface area was chosen as an adsorbent, for each CMK-3 obtained from different methods. Batch adsorption experiments were studied to determine the influence of pH, contact time, and initial dye concentration. The adsorption kinetics obeyed the pseudo-second-order model. All carbon-based adsorbents were observed to be quite effective for the removal of dye with adsorption percentage in the order of CP > CT > CGMT. The maximum adsorption capacities were 188.99 and 204.57 mg·g−1 for CT and CGMT, respectively. The comparative results of all carbon-based adsorbents show that CGMT can be applied as a low-cost alternative to CT for dye removal. HIGHLIGHTS CMK-3 was synthesized from gold mine waste (CGMT) for the first time.; The usage of CGMT as low-cost adsorbent for the removal of dye was investigated.; For comparison, other adsorbents synthesized from different methods were investigated as an adsorbent in the dye adsorption.; The specific surface area, pore volume and pore size dominate the adsorption capacity.; CGMT can be applied as a novel, low-cost and alternative adsorbent for dye removal.;Suheyl ErturkMuge Sari YilmazSabriye PiskinIWA Publishingarticlecmk-3dye adsorptiongold mine tailingslow-cost adsorbentrecycling wasteEnvironmental technology. Sanitary engineeringTD1-1066ENWater Science and Technology, Vol 83, Iss 6, Pp 1300-1314 (2021) |
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cmk-3 dye adsorption gold mine tailings low-cost adsorbent recycling waste Environmental technology. Sanitary engineering TD1-1066 |
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cmk-3 dye adsorption gold mine tailings low-cost adsorbent recycling waste Environmental technology. Sanitary engineering TD1-1066 Suheyl Erturk Muge Sari Yilmaz Sabriye Piskin Potential low-cost carbon-based adsorbent from gold mine tailings for anionic dye removal |
description |
In this study, a mesoporous carbon (CMK-3) was successfully synthesized using mesoporous silica (SBA-15) prepared from gold mine tailings (sample CGMT) for removal of anionic dye from aqueous solution. For comparison, CMK-3 was prepared by the same method from pure silica (sample CT), and the other CMK-3 sample was prepared by a one-pot route mixing with Pluronic P123 (sample CP). The effect of the carbonization time on the synthesis of all CMK-3 samples was investigated, and the samples were characterized by X-ray diffraction and N2 adsorption–desorption. The sample with the highest surface area was chosen as an adsorbent, for each CMK-3 obtained from different methods. Batch adsorption experiments were studied to determine the influence of pH, contact time, and initial dye concentration. The adsorption kinetics obeyed the pseudo-second-order model. All carbon-based adsorbents were observed to be quite effective for the removal of dye with adsorption percentage in the order of CP > CT > CGMT. The maximum adsorption capacities were 188.99 and 204.57 mg·g−1 for CT and CGMT, respectively. The comparative results of all carbon-based adsorbents show that CGMT can be applied as a low-cost alternative to CT for dye removal. HIGHLIGHTS
CMK-3 was synthesized from gold mine waste (CGMT) for the first time.;
The usage of CGMT as low-cost adsorbent for the removal of dye was investigated.;
For comparison, other adsorbents synthesized from different methods were investigated as an adsorbent in the dye adsorption.;
The specific surface area, pore volume and pore size dominate the adsorption capacity.;
CGMT can be applied as a novel, low-cost and alternative adsorbent for dye removal.; |
format |
article |
author |
Suheyl Erturk Muge Sari Yilmaz Sabriye Piskin |
author_facet |
Suheyl Erturk Muge Sari Yilmaz Sabriye Piskin |
author_sort |
Suheyl Erturk |
title |
Potential low-cost carbon-based adsorbent from gold mine tailings for anionic dye removal |
title_short |
Potential low-cost carbon-based adsorbent from gold mine tailings for anionic dye removal |
title_full |
Potential low-cost carbon-based adsorbent from gold mine tailings for anionic dye removal |
title_fullStr |
Potential low-cost carbon-based adsorbent from gold mine tailings for anionic dye removal |
title_full_unstemmed |
Potential low-cost carbon-based adsorbent from gold mine tailings for anionic dye removal |
title_sort |
potential low-cost carbon-based adsorbent from gold mine tailings for anionic dye removal |
publisher |
IWA Publishing |
publishDate |
2021 |
url |
https://doaj.org/article/874dd414fb7c42c58ebc64d7862b0891 |
work_keys_str_mv |
AT suheylerturk potentiallowcostcarbonbasedadsorbentfromgoldminetailingsforanionicdyeremoval AT mugesariyilmaz potentiallowcostcarbonbasedadsorbentfromgoldminetailingsforanionicdyeremoval AT sabriyepiskin potentiallowcostcarbonbasedadsorbentfromgoldminetailingsforanionicdyeremoval |
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