Multiyne chains chelating osmium via three metal-carbon σ bonds

Metal-carbon σ bonds mark the basis of organometallic chemistry, but the formation of multiple such bonds between single organic and metal entities remains a challenge. Here, the authors report a one-pot aromaticity-driven method to construct osmium-based multidentate complexes containing three meta...

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Autores principales:	Qingde Zhuo, Jianfeng Lin, Yuhui Hua, Xiaoxi Zhou, Yifan Shao, Shiyan Chen, Zhixin Chen, Jun Zhu, Hong Zhang, Haiping Xia
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/87ab51bae73f4caa8156ac60ca267953
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spelling	oai:doaj.org-article:87ab51bae73f4caa8156ac60ca2679532021-12-02T14:42:44ZMultiyne chains chelating osmium via three metal-carbon σ bonds10.1038/s41467-017-02120-z2041-1723https://doaj.org/article/87ab51bae73f4caa8156ac60ca2679532017-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-02120-zhttps://doaj.org/toc/2041-1723Metal-carbon σ bonds mark the basis of organometallic chemistry, but the formation of multiple such bonds between single organic and metal entities remains a challenge. Here, the authors report a one-pot aromaticity-driven method to construct osmium-based multidentate complexes containing three metal-carbon σ bonds from multiyn chains.Qingde ZhuoJianfeng LinYuhui HuaXiaoxi ZhouYifan ShaoShiyan ChenZhixin ChenJun ZhuHong ZhangHaiping XiaNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Qingde Zhuo Jianfeng Lin Yuhui Hua Xiaoxi Zhou Yifan Shao Shiyan Chen Zhixin Chen Jun Zhu Hong Zhang Haiping Xia Multiyne chains chelating osmium via three metal-carbon σ bonds
description	Metal-carbon σ bonds mark the basis of organometallic chemistry, but the formation of multiple such bonds between single organic and metal entities remains a challenge. Here, the authors report a one-pot aromaticity-driven method to construct osmium-based multidentate complexes containing three metal-carbon σ bonds from multiyn chains.
format	article
author	Qingde Zhuo Jianfeng Lin Yuhui Hua Xiaoxi Zhou Yifan Shao Shiyan Chen Zhixin Chen Jun Zhu Hong Zhang Haiping Xia
author_facet	Qingde Zhuo Jianfeng Lin Yuhui Hua Xiaoxi Zhou Yifan Shao Shiyan Chen Zhixin Chen Jun Zhu Hong Zhang Haiping Xia
author_sort	Qingde Zhuo
title	Multiyne chains chelating osmium via three metal-carbon σ bonds
title_short	Multiyne chains chelating osmium via three metal-carbon σ bonds
title_full	Multiyne chains chelating osmium via three metal-carbon σ bonds
title_fullStr	Multiyne chains chelating osmium via three metal-carbon σ bonds
title_full_unstemmed	Multiyne chains chelating osmium via three metal-carbon σ bonds
title_sort	multiyne chains chelating osmium via three metal-carbon σ bonds
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/87ab51bae73f4caa8156ac60ca267953
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Multiyne chains chelating osmium via three metal-carbon σ bonds

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