Solvophobicity-directed assembly of microporous molecular crystals

Porous organic crystals can be challenging to prepare, because in the absence of guests, they often collapse into denser, non-porous polymorphs. Here the formation of porous and non-porous polymorphs in different solvents is shown to depend on a solvophobic effect driven by dispersion interactions.

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Autores principales:	Hiroshi Yamagishi, Monika Tsunoda, Kohei Iwai, Kowit Hengphasatporn, Yasuteru Shigeta, Hiroyasu Sato, Yohei Yamamoto
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/87f6e6ad2ffd4b0a9009f24610e0934e
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spelling	oai:doaj.org-article:87f6e6ad2ffd4b0a9009f24610e0934e2021-12-02T16:45:28ZSolvophobicity-directed assembly of microporous molecular crystals10.1038/s42004-021-00561-82399-3669https://doaj.org/article/87f6e6ad2ffd4b0a9009f24610e0934e2021-08-01T00:00:00Zhttps://doi.org/10.1038/s42004-021-00561-8https://doaj.org/toc/2399-3669Porous organic crystals can be challenging to prepare, because in the absence of guests, they often collapse into denser, non-porous polymorphs. Here the formation of porous and non-porous polymorphs in different solvents is shown to depend on a solvophobic effect driven by dispersion interactions.Hiroshi YamagishiMonika TsunodaKohei IwaiKowit HengphasatpornYasuteru ShigetaHiroyasu SatoYohei YamamotoNature PortfolioarticleChemistryQD1-999ENCommunications Chemistry, Vol 4, Iss 1, Pp 1-8 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Chemistry QD1-999
spellingShingle	Chemistry QD1-999 Hiroshi Yamagishi Monika Tsunoda Kohei Iwai Kowit Hengphasatporn Yasuteru Shigeta Hiroyasu Sato Yohei Yamamoto Solvophobicity-directed assembly of microporous molecular crystals
description	Porous organic crystals can be challenging to prepare, because in the absence of guests, they often collapse into denser, non-porous polymorphs. Here the formation of porous and non-porous polymorphs in different solvents is shown to depend on a solvophobic effect driven by dispersion interactions.
format	article
author	Hiroshi Yamagishi Monika Tsunoda Kohei Iwai Kowit Hengphasatporn Yasuteru Shigeta Hiroyasu Sato Yohei Yamamoto
author_facet	Hiroshi Yamagishi Monika Tsunoda Kohei Iwai Kowit Hengphasatporn Yasuteru Shigeta Hiroyasu Sato Yohei Yamamoto
author_sort	Hiroshi Yamagishi
title	Solvophobicity-directed assembly of microporous molecular crystals
title_short	Solvophobicity-directed assembly of microporous molecular crystals
title_full	Solvophobicity-directed assembly of microporous molecular crystals
title_fullStr	Solvophobicity-directed assembly of microporous molecular crystals
title_full_unstemmed	Solvophobicity-directed assembly of microporous molecular crystals
title_sort	solvophobicity-directed assembly of microporous molecular crystals
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/87f6e6ad2ffd4b0a9009f24610e0934e
work_keys_str_mv	AT hiroshiyamagishi solvophobicitydirectedassemblyofmicroporousmolecularcrystals AT monikatsunoda solvophobicitydirectedassemblyofmicroporousmolecularcrystals AT koheiiwai solvophobicitydirectedassemblyofmicroporousmolecularcrystals AT kowithengphasatporn solvophobicitydirectedassemblyofmicroporousmolecularcrystals AT yasuterushigeta solvophobicitydirectedassemblyofmicroporousmolecularcrystals AT hiroyasusato solvophobicitydirectedassemblyofmicroporousmolecularcrystals AT yoheiyamamoto solvophobicitydirectedassemblyofmicroporousmolecularcrystals
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Solvophobicity-directed assembly of microporous molecular crystals

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