Solvophobicity-directed assembly of microporous molecular crystals
Porous organic crystals can be challenging to prepare, because in the absence of guests, they often collapse into denser, non-porous polymorphs. Here the formation of porous and non-porous polymorphs in different solvents is shown to depend on a solvophobic effect driven by dispersion interactions.
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| Autores principales: | , , , , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
Nature Portfolio
2021
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/87f6e6ad2ffd4b0a9009f24610e0934e |
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