Stable, active CO2 reduction to formate via redox-modulated stabilization of active sites

Stable electrochemical reduction to formate is still challenging. Here, the authors demonstrate a redox-modulation and active-site stabilization strategy for CO2 to formate conversion over 100 days of continuous operation at 100 mA/cm2 with a cathodic energy efficiency of 70%.

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Autores principales: Le Li, Adnan Ozden, Shuyi Guo, F. Pelayo Garcı́a de Arquer, Chuanhao Wang, Mingzhe Zhang, Jin Zhang, Haoyang Jiang, Wei Wang, Hao Dong, David Sinton, Edward H. Sargent, Miao Zhong
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Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/881645c19d0e4a4cb80c0a20183d9806
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spelling oai:doaj.org-article:881645c19d0e4a4cb80c0a20183d98062021-12-02T15:26:52ZStable, active CO2 reduction to formate via redox-modulated stabilization of active sites10.1038/s41467-021-25573-92041-1723https://doaj.org/article/881645c19d0e4a4cb80c0a20183d98062021-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-25573-9https://doaj.org/toc/2041-1723Stable electrochemical reduction to formate is still challenging. Here, the authors demonstrate a redox-modulation and active-site stabilization strategy for CO2 to formate conversion over 100 days of continuous operation at 100 mA/cm2 with a cathodic energy efficiency of 70%.Le LiAdnan OzdenShuyi GuoF. Pelayo Garcı́a de ArquerChuanhao WangMingzhe ZhangJin ZhangHaoyang JiangWei WangHao DongDavid SintonEdward H. SargentMiao ZhongNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Le Li
Adnan Ozden
Shuyi Guo
F. Pelayo Garcı́a de Arquer
Chuanhao Wang
Mingzhe Zhang
Jin Zhang
Haoyang Jiang
Wei Wang
Hao Dong
David Sinton
Edward H. Sargent
Miao Zhong
Stable, active CO2 reduction to formate via redox-modulated stabilization of active sites
description Stable electrochemical reduction to formate is still challenging. Here, the authors demonstrate a redox-modulation and active-site stabilization strategy for CO2 to formate conversion over 100 days of continuous operation at 100 mA/cm2 with a cathodic energy efficiency of 70%.
format article
author Le Li
Adnan Ozden
Shuyi Guo
F. Pelayo Garcı́a de Arquer
Chuanhao Wang
Mingzhe Zhang
Jin Zhang
Haoyang Jiang
Wei Wang
Hao Dong
David Sinton
Edward H. Sargent
Miao Zhong
author_facet Le Li
Adnan Ozden
Shuyi Guo
F. Pelayo Garcı́a de Arquer
Chuanhao Wang
Mingzhe Zhang
Jin Zhang
Haoyang Jiang
Wei Wang
Hao Dong
David Sinton
Edward H. Sargent
Miao Zhong
author_sort Le Li
title Stable, active CO2 reduction to formate via redox-modulated stabilization of active sites
title_short Stable, active CO2 reduction to formate via redox-modulated stabilization of active sites
title_full Stable, active CO2 reduction to formate via redox-modulated stabilization of active sites
title_fullStr Stable, active CO2 reduction to formate via redox-modulated stabilization of active sites
title_full_unstemmed Stable, active CO2 reduction to formate via redox-modulated stabilization of active sites
title_sort stable, active co2 reduction to formate via redox-modulated stabilization of active sites
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/881645c19d0e4a4cb80c0a20183d9806
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