Spectral Study of Pt (II), Cr (II) Polymeric Complexes of the Ligand N- Crotonyl -2- Hydroxy-Phenylazomethine
The polymeric complexes were obtained from the reaction of polymeric Schiff base.N-crotonyl-2-hydroxyphenylazomethine (HL), with divalent metals Pt (II), Cr (II). The modes of bonding and overall geometry of the complexes were determine through spectroscopic methods and compared with that reported f...
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Al-Khwarizmi College of Engineering – University of Baghdad
2013
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oai:doaj.org-article:88486049633942e98e790e1d709c8d6d2021-12-02T09:55:05ZSpectral Study of Pt (II), Cr (II) Polymeric Complexes of the Ligand N- Crotonyl -2- Hydroxy-Phenylazomethine1818-1171https://doaj.org/article/88486049633942e98e790e1d709c8d6d2013-12-01T00:00:00Zhttp://www.iasj.net/iasj?func=fulltext&aId=82636https://doaj.org/toc/1818-1171The polymeric complexes were obtained from the reaction of polymeric Schiff base.N-crotonyl-2-hydroxyphenylazomethine (HL), with divalent metals Pt (II), Cr (II). The modes of bonding and overall geometry of the complexes were determine through spectroscopic methods and compared with that reported from analogous monomeric ligand. This study revealed square planer geometry around the metal center for [Pt(L)Cl] and distorted octahedral geometry for Cr complex [Cr(L)Cl(H2O)2]. Alyaa Esam Mahdi Al-Khwarizmi College of Engineering – University of BaghdadarticleChemical engineeringTP155-156Engineering (General). Civil engineering (General)TA1-2040ENAl-Khawarizmi Engineering Journal, Vol 9, Iss 4, Pp 39-45 (2013) |
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DOAJ |
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DOAJ |
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EN |
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Chemical engineering TP155-156 Engineering (General). Civil engineering (General) TA1-2040 |
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Chemical engineering TP155-156 Engineering (General). Civil engineering (General) TA1-2040 Alyaa Esam Mahdi Spectral Study of Pt (II), Cr (II) Polymeric Complexes of the Ligand N- Crotonyl -2- Hydroxy-Phenylazomethine |
| description |
The polymeric complexes were obtained from the reaction of polymeric Schiff base.N-crotonyl-2-hydroxyphenylazomethine (HL), with divalent metals Pt (II), Cr (II). The modes of bonding and overall geometry of the complexes were determine through spectroscopic methods and compared with that reported from analogous monomeric ligand. This study revealed square planer geometry around the metal center for [Pt(L)Cl] and distorted octahedral geometry for Cr complex [Cr(L)Cl(H2O)2]. |
| format |
article |
| author |
Alyaa Esam Mahdi |
| author_facet |
Alyaa Esam Mahdi |
| author_sort |
Alyaa Esam Mahdi |
| title |
Spectral Study of Pt (II), Cr (II) Polymeric Complexes of the Ligand N- Crotonyl -2- Hydroxy-Phenylazomethine |
| title_short |
Spectral Study of Pt (II), Cr (II) Polymeric Complexes of the Ligand N- Crotonyl -2- Hydroxy-Phenylazomethine |
| title_full |
Spectral Study of Pt (II), Cr (II) Polymeric Complexes of the Ligand N- Crotonyl -2- Hydroxy-Phenylazomethine |
| title_fullStr |
Spectral Study of Pt (II), Cr (II) Polymeric Complexes of the Ligand N- Crotonyl -2- Hydroxy-Phenylazomethine |
| title_full_unstemmed |
Spectral Study of Pt (II), Cr (II) Polymeric Complexes of the Ligand N- Crotonyl -2- Hydroxy-Phenylazomethine |
| title_sort |
spectral study of pt (ii), cr (ii) polymeric complexes of the ligand n- crotonyl -2- hydroxy-phenylazomethine |
| publisher |
Al-Khwarizmi College of Engineering – University of Baghdad |
| publishDate |
2013 |
| url |
https://doaj.org/article/88486049633942e98e790e1d709c8d6d |
| work_keys_str_mv |
AT alyaaesammahdi spectralstudyofptiicriipolymericcomplexesoftheligandncrotonyl2hydroxyphenylazomethine |
| _version_ |
1718397891591012352 |