TRANSFORMACIÓN ENZIMÁTICA DE LA ESTRUCTURA CRISTALINA DEL COPOLÍMERO POLIETIL-VINIL ALCOHOL (EVOH)

Changes in the crystalline structure of the copolymer poly(ethylene-co-vinyl alcohol) (EVOH) that occurs during the enzymatic fermentation system with the fungus Phanerochaete chrysosoporium were studied. This fungus has a powerful group of oxidative enzymes that had been used for several processes...

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Autores principales: Carolina ARBOLEDA E., Freimar SEGURA S., Amanda I. MEJÍA G.
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Lenguaje:EN
Publicado: Universidad de Antioquia 2009
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Acceso en línea:https://doaj.org/article/8892b9d038fc4dadac49384bfb2fd752
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spelling oai:doaj.org-article:8892b9d038fc4dadac49384bfb2fd7522021-11-19T04:21:48ZTRANSFORMACIÓN ENZIMÁTICA DE LA ESTRUCTURA CRISTALINA DEL COPOLÍMERO POLIETIL-VINIL ALCOHOL (EVOH)0121-40042145-2660https://doaj.org/article/8892b9d038fc4dadac49384bfb2fd7522009-02-01T00:00:00Zhttps://revistas.udea.edu.co/index.php/vitae/article/view/565https://doaj.org/toc/0121-4004https://doaj.org/toc/2145-2660Changes in the crystalline structure of the copolymer poly(ethylene-co-vinyl alcohol) (EVOH) that occurs during the enzymatic fermentation system with the fungus Phanerochaete chrysosoporium were studied. This fungus has a powerful group of oxidative enzymes that had been used for several processes of environmental pollutants degradation. In order to use the enzymatic system of the fungus to improve degradation, films of the copolymer are inoculated and maintained in a solid state fermentation (SSF) system using as substrate a mixture of agroindustrial corn wastes with an initial humidity of 90%, during forty days. Analyses of the films were made at different times of fermentation. The effect on the chemical structure of the polymer was studied by using FTIR-spectroscopy with attenuated total reflection (ATR) and changes in the crystalline structure were determined by differential scan calorimetry DSC and X-ray diffraction technique. The lignin peroxidase (LiP) activity was followed by UV-spectrophotometry. We concluded that after 20 days of fermentation the copolymer has lost 50 percent of the initial crystalline structure. Carolina ARBOLEDA E.Freimar SEGURA S.Amanda I. MEJÍA G.Universidad de Antioquiaarticlepoly(ethylene-co-vinyl alcohol)lignin peroxidasePhanerochaete chrysosporiumcrystallineFood processing and manufactureTP368-456Pharmaceutical industryHD9665-9675ENVitae, Vol 14, Iss 1 (2009)
institution DOAJ
collection DOAJ
language EN
topic poly(ethylene-co-vinyl alcohol)
lignin peroxidase
Phanerochaete chrysosporium
crystalline
Food processing and manufacture
TP368-456
Pharmaceutical industry
HD9665-9675
spellingShingle poly(ethylene-co-vinyl alcohol)
lignin peroxidase
Phanerochaete chrysosporium
crystalline
Food processing and manufacture
TP368-456
Pharmaceutical industry
HD9665-9675
Carolina ARBOLEDA E.
Freimar SEGURA S.
Amanda I. MEJÍA G.
TRANSFORMACIÓN ENZIMÁTICA DE LA ESTRUCTURA CRISTALINA DEL COPOLÍMERO POLIETIL-VINIL ALCOHOL (EVOH)
description Changes in the crystalline structure of the copolymer poly(ethylene-co-vinyl alcohol) (EVOH) that occurs during the enzymatic fermentation system with the fungus Phanerochaete chrysosoporium were studied. This fungus has a powerful group of oxidative enzymes that had been used for several processes of environmental pollutants degradation. In order to use the enzymatic system of the fungus to improve degradation, films of the copolymer are inoculated and maintained in a solid state fermentation (SSF) system using as substrate a mixture of agroindustrial corn wastes with an initial humidity of 90%, during forty days. Analyses of the films were made at different times of fermentation. The effect on the chemical structure of the polymer was studied by using FTIR-spectroscopy with attenuated total reflection (ATR) and changes in the crystalline structure were determined by differential scan calorimetry DSC and X-ray diffraction technique. The lignin peroxidase (LiP) activity was followed by UV-spectrophotometry. We concluded that after 20 days of fermentation the copolymer has lost 50 percent of the initial crystalline structure.
format article
author Carolina ARBOLEDA E.
Freimar SEGURA S.
Amanda I. MEJÍA G.
author_facet Carolina ARBOLEDA E.
Freimar SEGURA S.
Amanda I. MEJÍA G.
author_sort Carolina ARBOLEDA E.
title TRANSFORMACIÓN ENZIMÁTICA DE LA ESTRUCTURA CRISTALINA DEL COPOLÍMERO POLIETIL-VINIL ALCOHOL (EVOH)
title_short TRANSFORMACIÓN ENZIMÁTICA DE LA ESTRUCTURA CRISTALINA DEL COPOLÍMERO POLIETIL-VINIL ALCOHOL (EVOH)
title_full TRANSFORMACIÓN ENZIMÁTICA DE LA ESTRUCTURA CRISTALINA DEL COPOLÍMERO POLIETIL-VINIL ALCOHOL (EVOH)
title_fullStr TRANSFORMACIÓN ENZIMÁTICA DE LA ESTRUCTURA CRISTALINA DEL COPOLÍMERO POLIETIL-VINIL ALCOHOL (EVOH)
title_full_unstemmed TRANSFORMACIÓN ENZIMÁTICA DE LA ESTRUCTURA CRISTALINA DEL COPOLÍMERO POLIETIL-VINIL ALCOHOL (EVOH)
title_sort transformación enzimática de la estructura cristalina del copolímero polietil-vinil alcohol (evoh)
publisher Universidad de Antioquia
publishDate 2009
url https://doaj.org/article/8892b9d038fc4dadac49384bfb2fd752
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