Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight

Organocatalytic atom transfer radical polymerization (O-ATRP) is attractive due to its metal-free nature but catalysts are rarely applied at a low loading. Here the authors introduce a catalyst design logic based on heteroatom-doping of polycyclic arenes, which led to the discovery of oxygen-doped a...

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Autores principales:	Qiang Ma, Jinshuai Song, Xun Zhang, Yu Jiang, Li Ji, Saihu Liao
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/88be05f482a64236a23650a990086e8b
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spelling	oai:doaj.org-article:88be05f482a64236a23650a990086e8b2021-12-02T14:19:11ZMetal-free atom transfer radical polymerization with ppm catalyst loading under sunlight10.1038/s41467-020-20645-82041-1723https://doaj.org/article/88be05f482a64236a23650a990086e8b2021-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-20645-8https://doaj.org/toc/2041-1723Organocatalytic atom transfer radical polymerization (O-ATRP) is attractive due to its metal-free nature but catalysts are rarely applied at a low loading. Here the authors introduce a catalyst design logic based on heteroatom-doping of polycyclic arenes, which led to the discovery of oxygen-doped anthanthrene as an organic photoredox catalysts for O-ATRP.Qiang MaJinshuai SongXun ZhangYu JiangLi JiSaihu LiaoNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Qiang Ma Jinshuai Song Xun Zhang Yu Jiang Li Ji Saihu Liao Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight
description	Organocatalytic atom transfer radical polymerization (O-ATRP) is attractive due to its metal-free nature but catalysts are rarely applied at a low loading. Here the authors introduce a catalyst design logic based on heteroatom-doping of polycyclic arenes, which led to the discovery of oxygen-doped anthanthrene as an organic photoredox catalysts for O-ATRP.
format	article
author	Qiang Ma Jinshuai Song Xun Zhang Yu Jiang Li Ji Saihu Liao
author_facet	Qiang Ma Jinshuai Song Xun Zhang Yu Jiang Li Ji Saihu Liao
author_sort	Qiang Ma
title	Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight
title_short	Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight
title_full	Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight
title_fullStr	Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight
title_full_unstemmed	Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight
title_sort	metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/88be05f482a64236a23650a990086e8b
work_keys_str_mv	AT qiangma metalfreeatomtransferradicalpolymerizationwithppmcatalystloadingundersunlight AT jinshuaisong metalfreeatomtransferradicalpolymerizationwithppmcatalystloadingundersunlight AT xunzhang metalfreeatomtransferradicalpolymerizationwithppmcatalystloadingundersunlight AT yujiang metalfreeatomtransferradicalpolymerizationwithppmcatalystloadingundersunlight AT liji metalfreeatomtransferradicalpolymerizationwithppmcatalystloadingundersunlight AT saihuliao metalfreeatomtransferradicalpolymerizationwithppmcatalystloadingundersunlight
_version_	1718391617940881408

Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight

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