Heterogeneous Catalytic Oxidation of Amides to Imides by Manganese Oxides

Abstract Herein, we report a one-step peroxide mediated heterogeneous catalytic oxidation of amides to imides utilizing a series of manganese oxides. Among them, Cs/Mn2O3 was found to be the most active catalyst for the selective partial oxidation of N-benzylbenzamide to diphenyl imide. We have been...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Sourav Biswas, Harshul S. Khanna, Quddus A. Nizami, Donald R. Caldwell, Katherine T. Cavanaugh, Amy R. Howell, Sumathy Raman, Steven L. Suib, Partha Nandi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Heterogeneous Catalytic Oxidation Amorphous Manganese Oxide (AMO) Imide Product Manganese Oxide Octahedral Molecular Sieve Benzylamide Medicine R Science Q
Acceso en línea:	https://doaj.org/article/88c076a7233e4b528f60fabbe04fa910
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:88c076a7233e4b528f60fabbe04fa910
record_format	dspace
spelling	oai:doaj.org-article:88c076a7233e4b528f60fabbe04fa9102021-12-02T15:08:26ZHeterogeneous Catalytic Oxidation of Amides to Imides by Manganese Oxides10.1038/s41598-018-31729-32045-2322https://doaj.org/article/88c076a7233e4b528f60fabbe04fa9102018-09-01T00:00:00Zhttps://doi.org/10.1038/s41598-018-31729-3https://doaj.org/toc/2045-2322Abstract Herein, we report a one-step peroxide mediated heterogeneous catalytic oxidation of amides to imides utilizing a series of manganese oxides. Among them, Cs/Mn2O3 was found to be the most active catalyst for the selective partial oxidation of N-benzylbenzamide to diphenyl imide. We have been able to apply an optimized oxidation method to other aromatic substrates. The feasibility of using air as an oxidant, the heterogeneous nature, inexpensive catalytic materials, respectable turnover numbers, and chemoselectivity to imides make this methodology an attractive choice for functional group transformations of amides to imides.Sourav BiswasHarshul S. KhannaQuddus A. NizamiDonald R. CaldwellKatherine T. CavanaughAmy R. HowellSumathy RamanSteven L. SuibPartha NandiNature PortfolioarticleHeterogeneous Catalytic OxidationAmorphous Manganese Oxide (AMO)Imide ProductManganese Oxide Octahedral Molecular SieveBenzylamideMedicineRScienceQENScientific Reports, Vol 8, Iss 1, Pp 1-8 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Heterogeneous Catalytic Oxidation Amorphous Manganese Oxide (AMO) Imide Product Manganese Oxide Octahedral Molecular Sieve Benzylamide Medicine R Science Q
spellingShingle	Heterogeneous Catalytic Oxidation Amorphous Manganese Oxide (AMO) Imide Product Manganese Oxide Octahedral Molecular Sieve Benzylamide Medicine R Science Q Sourav Biswas Harshul S. Khanna Quddus A. Nizami Donald R. Caldwell Katherine T. Cavanaugh Amy R. Howell Sumathy Raman Steven L. Suib Partha Nandi Heterogeneous Catalytic Oxidation of Amides to Imides by Manganese Oxides
description	Abstract Herein, we report a one-step peroxide mediated heterogeneous catalytic oxidation of amides to imides utilizing a series of manganese oxides. Among them, Cs/Mn2O3 was found to be the most active catalyst for the selective partial oxidation of N-benzylbenzamide to diphenyl imide. We have been able to apply an optimized oxidation method to other aromatic substrates. The feasibility of using air as an oxidant, the heterogeneous nature, inexpensive catalytic materials, respectable turnover numbers, and chemoselectivity to imides make this methodology an attractive choice for functional group transformations of amides to imides.
format	article
author	Sourav Biswas Harshul S. Khanna Quddus A. Nizami Donald R. Caldwell Katherine T. Cavanaugh Amy R. Howell Sumathy Raman Steven L. Suib Partha Nandi
author_facet	Sourav Biswas Harshul S. Khanna Quddus A. Nizami Donald R. Caldwell Katherine T. Cavanaugh Amy R. Howell Sumathy Raman Steven L. Suib Partha Nandi
author_sort	Sourav Biswas
title	Heterogeneous Catalytic Oxidation of Amides to Imides by Manganese Oxides
title_short	Heterogeneous Catalytic Oxidation of Amides to Imides by Manganese Oxides
title_full	Heterogeneous Catalytic Oxidation of Amides to Imides by Manganese Oxides
title_fullStr	Heterogeneous Catalytic Oxidation of Amides to Imides by Manganese Oxides
title_full_unstemmed	Heterogeneous Catalytic Oxidation of Amides to Imides by Manganese Oxides
title_sort	heterogeneous catalytic oxidation of amides to imides by manganese oxides
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/88c076a7233e4b528f60fabbe04fa910
work_keys_str_mv	AT souravbiswas heterogeneouscatalyticoxidationofamidestoimidesbymanganeseoxides AT harshulskhanna heterogeneouscatalyticoxidationofamidestoimidesbymanganeseoxides AT quddusanizami heterogeneouscatalyticoxidationofamidestoimidesbymanganeseoxides AT donaldrcaldwell heterogeneouscatalyticoxidationofamidestoimidesbymanganeseoxides AT katherinetcavanaugh heterogeneouscatalyticoxidationofamidestoimidesbymanganeseoxides AT amyrhowell heterogeneouscatalyticoxidationofamidestoimidesbymanganeseoxides AT sumathyraman heterogeneouscatalyticoxidationofamidestoimidesbymanganeseoxides AT stevenlsuib heterogeneouscatalyticoxidationofamidestoimidesbymanganeseoxides AT parthanandi heterogeneouscatalyticoxidationofamidestoimidesbymanganeseoxides
_version_	1718388132054827008

Heterogeneous Catalytic Oxidation of Amides to Imides by Manganese Oxides

Ejemplares similares