Synthesis and Characterization of 2,3-Diaminomaleonitrile Derivatives by One-Pot Schiff Base Reaction and Their Application in Dye Synthesized Solar Cells

In a one-pot reaction, three new 2,3-diaminomaleonitrile (DAMN) derivative dyes were prepared by simple Schiff base reaction. The compounds were designed as a sensitizer in dye synthesizes solar cells (DSSCs). Many conditions have been used to provide the methodology to get the best yield. The prepa...

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Autores principales:	Saifaldeen Muwafag Abdalhadi, Asmaa Yahya Al-Baitai, Hazim Abdulrazzaq Al-Zubaidi
Formato:	article
Lenguaje:	EN
Publicado:	Department of Chemistry, Universitas Gadjah Mada 2020
Materias:	one-pot reaction 2,3-diaminomaleonitrile schiff base dsscs Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/8914cfde5c4e4f628dc4c4dc692c6437
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spelling	oai:doaj.org-article:8914cfde5c4e4f628dc4c4dc692c64372021-12-02T14:51:23ZSynthesis and Characterization of 2,3-Diaminomaleonitrile Derivatives by One-Pot Schiff Base Reaction and Their Application in Dye Synthesized Solar Cells1411-94202460-157810.22146/ijc.57535https://doaj.org/article/8914cfde5c4e4f628dc4c4dc692c64372020-12-01T00:00:00Zhttps://jurnal.ugm.ac.id/ijc/article/view/57535https://doaj.org/toc/1411-9420https://doaj.org/toc/2460-1578In a one-pot reaction, three new 2,3-diaminomaleonitrile (DAMN) derivative dyes were prepared by simple Schiff base reaction. The compounds were designed as a sensitizer in dye synthesizes solar cells (DSSCs). Many conditions have been used to provide the methodology to get the best yield. The prepared dyes were characterized by melting point, elemental microanalysis, mass spectroscopy, FT-IR, 1H-NMR, and UV-Vis spectroscopy. A computational study was carried out to support our results. The DSSC data was shown the best performance for SA3 dye with 0.38% efficiency at AM 1.5 then SA2 with 0.22% and the last dye is SA1 with 0.09%, compared to control cell (N719) 5.4%.Saifaldeen Muwafag AbdalhadiAsmaa Yahya Al-BaitaiHazim Abdulrazzaq Al-ZubaidiDepartment of Chemistry, Universitas Gadjah Madaarticleone-pot reaction2,3-diaminomaleonitrileschiff basedsscsChemistryQD1-999ENIndonesian Journal of Chemistry, Vol 21, Iss 2, Pp 443-451 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	one-pot reaction 2,3-diaminomaleonitrile schiff base dsscs Chemistry QD1-999
spellingShingle	one-pot reaction 2,3-diaminomaleonitrile schiff base dsscs Chemistry QD1-999 Saifaldeen Muwafag Abdalhadi Asmaa Yahya Al-Baitai Hazim Abdulrazzaq Al-Zubaidi Synthesis and Characterization of 2,3-Diaminomaleonitrile Derivatives by One-Pot Schiff Base Reaction and Their Application in Dye Synthesized Solar Cells
description	In a one-pot reaction, three new 2,3-diaminomaleonitrile (DAMN) derivative dyes were prepared by simple Schiff base reaction. The compounds were designed as a sensitizer in dye synthesizes solar cells (DSSCs). Many conditions have been used to provide the methodology to get the best yield. The prepared dyes were characterized by melting point, elemental microanalysis, mass spectroscopy, FT-IR, 1H-NMR, and UV-Vis spectroscopy. A computational study was carried out to support our results. The DSSC data was shown the best performance for SA3 dye with 0.38% efficiency at AM 1.5 then SA2 with 0.22% and the last dye is SA1 with 0.09%, compared to control cell (N719) 5.4%.
format	article
author	Saifaldeen Muwafag Abdalhadi Asmaa Yahya Al-Baitai Hazim Abdulrazzaq Al-Zubaidi
author_facet	Saifaldeen Muwafag Abdalhadi Asmaa Yahya Al-Baitai Hazim Abdulrazzaq Al-Zubaidi
author_sort	Saifaldeen Muwafag Abdalhadi
title	Synthesis and Characterization of 2,3-Diaminomaleonitrile Derivatives by One-Pot Schiff Base Reaction and Their Application in Dye Synthesized Solar Cells
title_short	Synthesis and Characterization of 2,3-Diaminomaleonitrile Derivatives by One-Pot Schiff Base Reaction and Their Application in Dye Synthesized Solar Cells
title_full	Synthesis and Characterization of 2,3-Diaminomaleonitrile Derivatives by One-Pot Schiff Base Reaction and Their Application in Dye Synthesized Solar Cells
title_fullStr	Synthesis and Characterization of 2,3-Diaminomaleonitrile Derivatives by One-Pot Schiff Base Reaction and Their Application in Dye Synthesized Solar Cells
title_full_unstemmed	Synthesis and Characterization of 2,3-Diaminomaleonitrile Derivatives by One-Pot Schiff Base Reaction and Their Application in Dye Synthesized Solar Cells
title_sort	synthesis and characterization of 2,3-diaminomaleonitrile derivatives by one-pot schiff base reaction and their application in dye synthesized solar cells
publisher	Department of Chemistry, Universitas Gadjah Mada
publishDate	2020
url	https://doaj.org/article/8914cfde5c4e4f628dc4c4dc692c6437
work_keys_str_mv	AT saifaldeenmuwafagabdalhadi synthesisandcharacterizationof23diaminomaleonitrilederivativesbyonepotschiffbasereactionandtheirapplicationindyesynthesizedsolarcells AT asmaayahyaalbaitai synthesisandcharacterizationof23diaminomaleonitrilederivativesbyonepotschiffbasereactionandtheirapplicationindyesynthesizedsolarcells AT hazimabdulrazzaqalzubaidi synthesisandcharacterizationof23diaminomaleonitrilederivativesbyonepotschiffbasereactionandtheirapplicationindyesynthesizedsolarcells
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Synthesis and Characterization of 2,3-Diaminomaleonitrile Derivatives by One-Pot Schiff Base Reaction and Their Application in Dye Synthesized Solar Cells

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