The role of π-blocking hydride ligands in a pressure-induced insulator-to-metal phase transition in SrVO2H
Incorporating hydride anions into transition metal oxides can dramatically affect their structural and electronic properties. Here the authors reveal a pressure-induced insulator-to-metal transition in SrVO2H and show that the compressibility of hydride anions without π-symmetry valence orbitals cau...
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| Autores principales: | , , , , , , , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
Nature Portfolio
2017
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/89473b4d636c465bbaf94dccf98c4866 |
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| Sumario: | Incorporating hydride anions into transition metal oxides can dramatically affect their structural and electronic properties. Here the authors reveal a pressure-induced insulator-to-metal transition in SrVO2H and show that the compressibility of hydride anions without π-symmetry valence orbitals causes them to act as π-blockers. |
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