The role of π-blocking hydride ligands in a pressure-induced insulator-to-metal phase transition in SrVO2H

Incorporating hydride anions into transition metal oxides can dramatically affect their structural and electronic properties. Here the authors reveal a pressure-induced insulator-to-metal transition in SrVO2H and show that the compressibility of hydride anions without π-symmetry valence orbitals cau...

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Autores principales:	Takafumi Yamamoto, Dihao Zeng, Takateru Kawakami, Vaida Arcisauskaite, Kanami Yata, Midori Amano Patino, Nana Izumo, John E. McGrady, Hiroshi Kageyama, Michael A. Hayward
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/89473b4d636c465bbaf94dccf98c4866
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spelling	oai:doaj.org-article:89473b4d636c465bbaf94dccf98c48662021-12-02T15:38:59ZThe role of π-blocking hydride ligands in a pressure-induced insulator-to-metal phase transition in SrVO2H10.1038/s41467-017-01301-02041-1723https://doaj.org/article/89473b4d636c465bbaf94dccf98c48662017-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-01301-0https://doaj.org/toc/2041-1723Incorporating hydride anions into transition metal oxides can dramatically affect their structural and electronic properties. Here the authors reveal a pressure-induced insulator-to-metal transition in SrVO2H and show that the compressibility of hydride anions without π-symmetry valence orbitals causes them to act as π-blockers.Takafumi YamamotoDihao ZengTakateru KawakamiVaida ArcisauskaiteKanami YataMidori Amano PatinoNana IzumoJohn E. McGradyHiroshi KageyamaMichael A. HaywardNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Takafumi Yamamoto Dihao Zeng Takateru Kawakami Vaida Arcisauskaite Kanami Yata Midori Amano Patino Nana Izumo John E. McGrady Hiroshi Kageyama Michael A. Hayward The role of π-blocking hydride ligands in a pressure-induced insulator-to-metal phase transition in SrVO2H
description	Incorporating hydride anions into transition metal oxides can dramatically affect their structural and electronic properties. Here the authors reveal a pressure-induced insulator-to-metal transition in SrVO2H and show that the compressibility of hydride anions without π-symmetry valence orbitals causes them to act as π-blockers.
format	article
author	Takafumi Yamamoto Dihao Zeng Takateru Kawakami Vaida Arcisauskaite Kanami Yata Midori Amano Patino Nana Izumo John E. McGrady Hiroshi Kageyama Michael A. Hayward
author_facet	Takafumi Yamamoto Dihao Zeng Takateru Kawakami Vaida Arcisauskaite Kanami Yata Midori Amano Patino Nana Izumo John E. McGrady Hiroshi Kageyama Michael A. Hayward
author_sort	Takafumi Yamamoto
title	The role of π-blocking hydride ligands in a pressure-induced insulator-to-metal phase transition in SrVO2H
title_short	The role of π-blocking hydride ligands in a pressure-induced insulator-to-metal phase transition in SrVO2H
title_full	The role of π-blocking hydride ligands in a pressure-induced insulator-to-metal phase transition in SrVO2H
title_fullStr	The role of π-blocking hydride ligands in a pressure-induced insulator-to-metal phase transition in SrVO2H
title_full_unstemmed	The role of π-blocking hydride ligands in a pressure-induced insulator-to-metal phase transition in SrVO2H
title_sort	role of π-blocking hydride ligands in a pressure-induced insulator-to-metal phase transition in srvo2h
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/89473b4d636c465bbaf94dccf98c4866
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The role of π-blocking hydride ligands in a pressure-induced insulator-to-metal phase transition in SrVO2H

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