A highly active Ni(II)-triadamantylphosphine catalyst for ultrahigh-molecular-weight polyethylene synthesis

Ultra-high molecular weight polyethylene is a desirable commodity. Here the authors show that a tri-1-adamantylphosphine-nickel complex, when exposed to alkyl aluminium activators, polymerizes ethylene to ultrahigh-molecular-weight polyethylene with initial activities reaching 3.8 million turnovers/...

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Autores principales:	Andrew L. Kocen, Maurice Brookhart, Olafs Daugulis
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/8980509c560843dc826fb054d03181a1
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spelling	oai:doaj.org-article:8980509c560843dc826fb054d03181a12021-12-02T16:58:25ZA highly active Ni(II)-triadamantylphosphine catalyst for ultrahigh-molecular-weight polyethylene synthesis10.1038/s41467-019-08309-82041-1723https://doaj.org/article/8980509c560843dc826fb054d03181a12019-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-08309-8https://doaj.org/toc/2041-1723Ultra-high molecular weight polyethylene is a desirable commodity. Here the authors show that a tri-1-adamantylphosphine-nickel complex, when exposed to alkyl aluminium activators, polymerizes ethylene to ultrahigh-molecular-weight polyethylene with initial activities reaching 3.8 million turnovers/h at 10 °C.Andrew L. KocenMaurice BrookhartOlafs DaugulisNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-6 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Andrew L. Kocen Maurice Brookhart Olafs Daugulis A highly active Ni(II)-triadamantylphosphine catalyst for ultrahigh-molecular-weight polyethylene synthesis
description	Ultra-high molecular weight polyethylene is a desirable commodity. Here the authors show that a tri-1-adamantylphosphine-nickel complex, when exposed to alkyl aluminium activators, polymerizes ethylene to ultrahigh-molecular-weight polyethylene with initial activities reaching 3.8 million turnovers/h at 10 °C.
format	article
author	Andrew L. Kocen Maurice Brookhart Olafs Daugulis
author_facet	Andrew L. Kocen Maurice Brookhart Olafs Daugulis
author_sort	Andrew L. Kocen
title	A highly active Ni(II)-triadamantylphosphine catalyst for ultrahigh-molecular-weight polyethylene synthesis
title_short	A highly active Ni(II)-triadamantylphosphine catalyst for ultrahigh-molecular-weight polyethylene synthesis
title_full	A highly active Ni(II)-triadamantylphosphine catalyst for ultrahigh-molecular-weight polyethylene synthesis
title_fullStr	A highly active Ni(II)-triadamantylphosphine catalyst for ultrahigh-molecular-weight polyethylene synthesis
title_full_unstemmed	A highly active Ni(II)-triadamantylphosphine catalyst for ultrahigh-molecular-weight polyethylene synthesis
title_sort	highly active ni(ii)-triadamantylphosphine catalyst for ultrahigh-molecular-weight polyethylene synthesis
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/8980509c560843dc826fb054d03181a1
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A highly active Ni(II)-triadamantylphosphine catalyst for ultrahigh-molecular-weight polyethylene synthesis

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