A highly active Ni(II)-triadamantylphosphine catalyst for ultrahigh-molecular-weight polyethylene synthesis

Ultra-high molecular weight polyethylene is a desirable commodity. Here the authors show that a tri-1-adamantylphosphine-nickel complex, when exposed to alkyl aluminium activators, polymerizes ethylene to ultrahigh-molecular-weight polyethylene with initial activities reaching 3.8 million turnovers/...

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Autores principales: Andrew L. Kocen, Maurice Brookhart, Olafs Daugulis
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/8980509c560843dc826fb054d03181a1
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