Mesoporous Membrane Materials Based on Ultra-High-Molecular-Weight Polyethylene: From Synthesis to Applied Aspects

The development of new porous polymeric materials with nanoscale pore dimensions and controlled morphology presents a challenging problem of modern materials and membrane science, which should be based on scientifically justified approaches with the emphasis on ecological issues. This work offers a...

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Autores principales:	Olga V. Arzhakova, Andrei I. Nazarov, Arina R. Solovei, Alla A. Dolgova, Aleksandr Yu. Kopnov, Denis K. Chaplygin, Polina M. Tyubaeva, Alena Yu. Yarysheva
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	mesoporous polymer materials ultra-high-molecular-weight polyethylene environmental crazing water vapor permeability breathable materials polymeric membranes Chemical technology TP1-1185 Chemical engineering TP155-156
Acceso en línea:	https://doaj.org/article/8a291f44810449009aba9583be4cbfe3
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spelling	oai:doaj.org-article:8a291f44810449009aba9583be4cbfe32021-11-25T18:19:41ZMesoporous Membrane Materials Based on Ultra-High-Molecular-Weight Polyethylene: From Synthesis to Applied Aspects10.3390/membranes111108342077-0375https://doaj.org/article/8a291f44810449009aba9583be4cbfe32021-10-01T00:00:00Zhttps://www.mdpi.com/2077-0375/11/11/834https://doaj.org/toc/2077-0375The development of new porous polymeric materials with nanoscale pore dimensions and controlled morphology presents a challenging problem of modern materials and membrane science, which should be based on scientifically justified approaches with the emphasis on ecological issues. This work offers a facile and sustainable strategy allowing preparation of porous nanostructured materials based on ultra-high-molecular-weight polyethylene (UHMWPE) via the mechanism of environmental intercrystallite crazing and their detailed characterization by diverse physicochemical methods, including SEM, TEM, AFM, liquid and gas permeability, DSC, etc. The resultant porous UHMWPE materials are characterized by high porosity (up to ~45%), pore interconnectivity, nanoscale pore dimensions (below 10 nm), high water vapor permeability [1700 g/(m<sup>2</sup> × day)] and high gas permeability (the Gurley number ~300 s), selectivity, and good mechanical properties. The applied benefits of the advanced UHMWPE mesoporous materials as efficient membranes, breathable, waterproof, and insulating materials, light-weight materials with reduced density, gas capture and storage systems, porous substrates and scaffolds are discussed.Olga V. ArzhakovaAndrei I. NazarovArina R. SoloveiAlla A. DolgovaAleksandr Yu. KopnovDenis K. ChaplyginPolina M. TyubaevaAlena Yu. YaryshevaMDPI AGarticlemesoporous polymer materialsultra-high-molecular-weight polyethyleneenvironmental crazingwater vapor permeabilitybreathable materialspolymeric membranesChemical technologyTP1-1185Chemical engineeringTP155-156ENMembranes, Vol 11, Iss 834, p 834 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	mesoporous polymer materials ultra-high-molecular-weight polyethylene environmental crazing water vapor permeability breathable materials polymeric membranes Chemical technology TP1-1185 Chemical engineering TP155-156
spellingShingle	mesoporous polymer materials ultra-high-molecular-weight polyethylene environmental crazing water vapor permeability breathable materials polymeric membranes Chemical technology TP1-1185 Chemical engineering TP155-156 Olga V. Arzhakova Andrei I. Nazarov Arina R. Solovei Alla A. Dolgova Aleksandr Yu. Kopnov Denis K. Chaplygin Polina M. Tyubaeva Alena Yu. Yarysheva Mesoporous Membrane Materials Based on Ultra-High-Molecular-Weight Polyethylene: From Synthesis to Applied Aspects
description	The development of new porous polymeric materials with nanoscale pore dimensions and controlled morphology presents a challenging problem of modern materials and membrane science, which should be based on scientifically justified approaches with the emphasis on ecological issues. This work offers a facile and sustainable strategy allowing preparation of porous nanostructured materials based on ultra-high-molecular-weight polyethylene (UHMWPE) via the mechanism of environmental intercrystallite crazing and their detailed characterization by diverse physicochemical methods, including SEM, TEM, AFM, liquid and gas permeability, DSC, etc. The resultant porous UHMWPE materials are characterized by high porosity (up to ~45%), pore interconnectivity, nanoscale pore dimensions (below 10 nm), high water vapor permeability [1700 g/(m<sup>2</sup> × day)] and high gas permeability (the Gurley number ~300 s), selectivity, and good mechanical properties. The applied benefits of the advanced UHMWPE mesoporous materials as efficient membranes, breathable, waterproof, and insulating materials, light-weight materials with reduced density, gas capture and storage systems, porous substrates and scaffolds are discussed.
format	article
author	Olga V. Arzhakova Andrei I. Nazarov Arina R. Solovei Alla A. Dolgova Aleksandr Yu. Kopnov Denis K. Chaplygin Polina M. Tyubaeva Alena Yu. Yarysheva
author_facet	Olga V. Arzhakova Andrei I. Nazarov Arina R. Solovei Alla A. Dolgova Aleksandr Yu. Kopnov Denis K. Chaplygin Polina M. Tyubaeva Alena Yu. Yarysheva
author_sort	Olga V. Arzhakova
title	Mesoporous Membrane Materials Based on Ultra-High-Molecular-Weight Polyethylene: From Synthesis to Applied Aspects
title_short	Mesoporous Membrane Materials Based on Ultra-High-Molecular-Weight Polyethylene: From Synthesis to Applied Aspects
title_full	Mesoporous Membrane Materials Based on Ultra-High-Molecular-Weight Polyethylene: From Synthesis to Applied Aspects
title_fullStr	Mesoporous Membrane Materials Based on Ultra-High-Molecular-Weight Polyethylene: From Synthesis to Applied Aspects
title_full_unstemmed	Mesoporous Membrane Materials Based on Ultra-High-Molecular-Weight Polyethylene: From Synthesis to Applied Aspects
title_sort	mesoporous membrane materials based on ultra-high-molecular-weight polyethylene: from synthesis to applied aspects
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/8a291f44810449009aba9583be4cbfe3
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Mesoporous Membrane Materials Based on Ultra-High-Molecular-Weight Polyethylene: From Synthesis to Applied Aspects

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