Oxy-Steam Reforming of Liquefied Natural Gas (LNG) on Mono- and Bimetallic (Ag, Pt, Pd or Ru)/Ni Catalysts

This work presents, for the first time, the comparative physicochemical and reactivity studies of a range of bimetallic Pt-Ni, Pd-Ni, Ru-Ni, and Ag-Ni catalysts in the oxy-steam reforming (OSR) of liquefied natural gas (LNG) reaction towards hydrogen generation. In order to achieve the intended purp...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Pawel Mierczynski, Magdalena Mosinska, Waldemar Maniukiewicz, Krasimir Vasilev, Malgorzata Iwona Szynkowska-Jozwik
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	noble metal bimetallic catalyst nickel catalyst hydrogen production oxy-steam reforming LNG Chemical technology TP1-1185 Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/8a7475fdce4f412cb325d37c5871b858
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:8a7475fdce4f412cb325d37c5871b858
record_format	dspace
spelling	oai:doaj.org-article:8a7475fdce4f412cb325d37c5871b8582021-11-25T17:06:48ZOxy-Steam Reforming of Liquefied Natural Gas (LNG) on Mono- and Bimetallic (Ag, Pt, Pd or Ru)/Ni Catalysts10.3390/catal111114012073-4344https://doaj.org/article/8a7475fdce4f412cb325d37c5871b8582021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4344/11/11/1401https://doaj.org/toc/2073-4344This work presents, for the first time, the comparative physicochemical and reactivity studies of a range of bimetallic Pt-Ni, Pd-Ni, Ru-Ni, and Ag-Ni catalysts in the oxy-steam reforming (OSR) of liquefied natural gas (LNG) reaction towards hydrogen generation. In order to achieve the intended purpose of this work, a binary oxide CeO<sub>2</sub>·ZrO<sub>2</sub> (1:2) support was prepared via a co-precipitation method. The catalysts’ physicochemical properties were studied using X-ray diffraction (XRD), BET, TPR-H<sub>2</sub>, TPD-NH<sub>3</sub>, SEM-EDS and XPS methods. The highest activity in the studied process was exhibited by the 1%Pt-5%Ni catalyst supported on CeO<sub>2</sub>·ZrO<sub>2</sub> (1:2) system. The highest activity of this system is explained by the specific interactions occurring between the components of the active phase and between the components of the active phase and the carrier itself. The activity results showed that this catalytic system exhibited above 71% of the methane conversion at 600 °C and 60% yield of hydrogen formation. The results of this work demonstrate that the Pt-Ni and Ru-Ni catalytic systems hold promise to be applied in the production of hydrogen to power solid oxide fuel cells.Pawel MierczynskiMagdalena MosinskaWaldemar ManiukiewiczKrasimir VasilevMalgorzata Iwona Szynkowska-JozwikMDPI AGarticlenoble metalbimetallic catalystnickel catalysthydrogen productionoxy-steam reformingLNGChemical technologyTP1-1185ChemistryQD1-999ENCatalysts, Vol 11, Iss 1401, p 1401 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	noble metal bimetallic catalyst nickel catalyst hydrogen production oxy-steam reforming LNG Chemical technology TP1-1185 Chemistry QD1-999
spellingShingle	noble metal bimetallic catalyst nickel catalyst hydrogen production oxy-steam reforming LNG Chemical technology TP1-1185 Chemistry QD1-999 Pawel Mierczynski Magdalena Mosinska Waldemar Maniukiewicz Krasimir Vasilev Malgorzata Iwona Szynkowska-Jozwik Oxy-Steam Reforming of Liquefied Natural Gas (LNG) on Mono- and Bimetallic (Ag, Pt, Pd or Ru)/Ni Catalysts
description	This work presents, for the first time, the comparative physicochemical and reactivity studies of a range of bimetallic Pt-Ni, Pd-Ni, Ru-Ni, and Ag-Ni catalysts in the oxy-steam reforming (OSR) of liquefied natural gas (LNG) reaction towards hydrogen generation. In order to achieve the intended purpose of this work, a binary oxide CeO<sub>2</sub>·ZrO<sub>2</sub> (1:2) support was prepared via a co-precipitation method. The catalysts’ physicochemical properties were studied using X-ray diffraction (XRD), BET, TPR-H<sub>2</sub>, TPD-NH<sub>3</sub>, SEM-EDS and XPS methods. The highest activity in the studied process was exhibited by the 1%Pt-5%Ni catalyst supported on CeO<sub>2</sub>·ZrO<sub>2</sub> (1:2) system. The highest activity of this system is explained by the specific interactions occurring between the components of the active phase and between the components of the active phase and the carrier itself. The activity results showed that this catalytic system exhibited above 71% of the methane conversion at 600 °C and 60% yield of hydrogen formation. The results of this work demonstrate that the Pt-Ni and Ru-Ni catalytic systems hold promise to be applied in the production of hydrogen to power solid oxide fuel cells.
format	article
author	Pawel Mierczynski Magdalena Mosinska Waldemar Maniukiewicz Krasimir Vasilev Malgorzata Iwona Szynkowska-Jozwik
author_facet	Pawel Mierczynski Magdalena Mosinska Waldemar Maniukiewicz Krasimir Vasilev Malgorzata Iwona Szynkowska-Jozwik
author_sort	Pawel Mierczynski
title	Oxy-Steam Reforming of Liquefied Natural Gas (LNG) on Mono- and Bimetallic (Ag, Pt, Pd or Ru)/Ni Catalysts
title_short	Oxy-Steam Reforming of Liquefied Natural Gas (LNG) on Mono- and Bimetallic (Ag, Pt, Pd or Ru)/Ni Catalysts
title_full	Oxy-Steam Reforming of Liquefied Natural Gas (LNG) on Mono- and Bimetallic (Ag, Pt, Pd or Ru)/Ni Catalysts
title_fullStr	Oxy-Steam Reforming of Liquefied Natural Gas (LNG) on Mono- and Bimetallic (Ag, Pt, Pd or Ru)/Ni Catalysts
title_full_unstemmed	Oxy-Steam Reforming of Liquefied Natural Gas (LNG) on Mono- and Bimetallic (Ag, Pt, Pd or Ru)/Ni Catalysts
title_sort	oxy-steam reforming of liquefied natural gas (lng) on mono- and bimetallic (ag, pt, pd or ru)/ni catalysts
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/8a7475fdce4f412cb325d37c5871b858
work_keys_str_mv	AT pawelmierczynski oxysteamreformingofliquefiednaturalgaslngonmonoandbimetallicagptpdorrunicatalysts AT magdalenamosinska oxysteamreformingofliquefiednaturalgaslngonmonoandbimetallicagptpdorrunicatalysts AT waldemarmaniukiewicz oxysteamreformingofliquefiednaturalgaslngonmonoandbimetallicagptpdorrunicatalysts AT krasimirvasilev oxysteamreformingofliquefiednaturalgaslngonmonoandbimetallicagptpdorrunicatalysts AT malgorzataiwonaszynkowskajozwik oxysteamreformingofliquefiednaturalgaslngonmonoandbimetallicagptpdorrunicatalysts
_version_	1718412726185754624

Oxy-Steam Reforming of Liquefied Natural Gas (LNG) on Mono- and Bimetallic (Ag, Pt, Pd or Ru)/Ni Catalysts

Ejemplares similares