Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation

Hydroformylation of 1,2-disubstituted alkenes usually occurs at the α position of the directing heteroatom. Here, the authors report the asymmetric rhodium-catalyzed hydroformylation of 1,2-disubstituted alkenylsilanes with excellent regioselectivity at the β position (relative to the silicon hetero...

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Auteurs principaux:	Cai You, Xiuxiu Li, Yuhong Yang, Yu-Sheng Yang, Xuefeng Tan, Shuailong Li, Biao Wei, Hui Lv, Lung-Wa Chung, Xumu Zhang
Format:	article
Langue:	EN
Publié:	Nature Portfolio 2018
Sujets:	Science Q
Accès en ligne:	https://doaj.org/article/8a8889051f1e44aa88f300938dd4c0c1
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id	oai:doaj.org-article:8a8889051f1e44aa88f300938dd4c0c1
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spelling	oai:doaj.org-article:8a8889051f1e44aa88f300938dd4c0c12021-12-02T15:33:54ZSilicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation10.1038/s41467-018-04277-72041-1723https://doaj.org/article/8a8889051f1e44aa88f300938dd4c0c12018-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-04277-7https://doaj.org/toc/2041-1723Hydroformylation of 1,2-disubstituted alkenes usually occurs at the α position of the directing heteroatom. Here, the authors report the asymmetric rhodium-catalyzed hydroformylation of 1,2-disubstituted alkenylsilanes with excellent regioselectivity at the β position (relative to the silicon heteroatom) and enantioselectivity.Cai YouXiuxiu LiYuhong YangYu-Sheng YangXuefeng TanShuailong LiBiao WeiHui LvLung-Wa ChungXumu ZhangNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-9 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Cai You Xiuxiu Li Yuhong Yang Yu-Sheng Yang Xuefeng Tan Shuailong Li Biao Wei Hui Lv Lung-Wa Chung Xumu Zhang Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation
description	Hydroformylation of 1,2-disubstituted alkenes usually occurs at the α position of the directing heteroatom. Here, the authors report the asymmetric rhodium-catalyzed hydroformylation of 1,2-disubstituted alkenylsilanes with excellent regioselectivity at the β position (relative to the silicon heteroatom) and enantioselectivity.
format	article
author	Cai You Xiuxiu Li Yuhong Yang Yu-Sheng Yang Xuefeng Tan Shuailong Li Biao Wei Hui Lv Lung-Wa Chung Xumu Zhang
author_facet	Cai You Xiuxiu Li Yuhong Yang Yu-Sheng Yang Xuefeng Tan Shuailong Li Biao Wei Hui Lv Lung-Wa Chung Xumu Zhang
author_sort	Cai You
title	Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation
title_short	Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation
title_full	Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation
title_fullStr	Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation
title_full_unstemmed	Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation
title_sort	silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/8a8889051f1e44aa88f300938dd4c0c1
work_keys_str_mv	AT caiyou siliconorientedregioandenantioselectiverhodiumcatalyzedhydroformylation AT xiuxiuli siliconorientedregioandenantioselectiverhodiumcatalyzedhydroformylation AT yuhongyang siliconorientedregioandenantioselectiverhodiumcatalyzedhydroformylation AT yushengyang siliconorientedregioandenantioselectiverhodiumcatalyzedhydroformylation AT xuefengtan siliconorientedregioandenantioselectiverhodiumcatalyzedhydroformylation AT shuailongli siliconorientedregioandenantioselectiverhodiumcatalyzedhydroformylation AT biaowei siliconorientedregioandenantioselectiverhodiumcatalyzedhydroformylation AT huilv siliconorientedregioandenantioselectiverhodiumcatalyzedhydroformylation AT lungwachung siliconorientedregioandenantioselectiverhodiumcatalyzedhydroformylation AT xumuzhang siliconorientedregioandenantioselectiverhodiumcatalyzedhydroformylation
_version_	1718386974706892800

Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation

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