A crystalline radical cation derived from Thiele’s hydrocarbon with redox range beyond 1 V

A crystalline radical cation derived from Thiele’s hydrocarbon with redox range beyond 1 V

Organic molecules that can access various redox states have potential applications in electronics, batteries, catalysis, among others. Here the authors report the preparation of an unsymmetrical organoboron analogue of Thiele’s hydrocarbon and study its one- and two-electron oxidation reactions; rem...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Ying Kai Loh, Petra Vasko, Caitilín McManus, Andreas Heilmann, William K. Myers, Simon Aldridge
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
Materias:
Science
Q
Acceso en línea:https://doaj.org/article/8ac58dd707a345c69481b8094024f506
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:doaj.org-article:8ac58dd707a345c69481b8094024f506
record_format dspace
spelling oai:doaj.org-article:8ac58dd707a345c69481b8094024f5062021-12-05T12:22:10ZA crystalline radical cation derived from Thiele’s hydrocarbon with redox range beyond 1 V10.1038/s41467-021-27104-y2041-1723https://doaj.org/article/8ac58dd707a345c69481b8094024f5062021-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-27104-yhttps://doaj.org/toc/2041-1723Organic molecules that can access various redox states have potential applications in electronics, batteries, catalysis, among others. Here the authors report the preparation of an unsymmetrical organoboron analogue of Thiele’s hydrocarbon and study its one- and two-electron oxidation reactions; remarkably, the radical cation is stable over a redox range of > 1 V and can also be isolated.Ying Kai LohPetra VaskoCaitilín McManusAndreas HeilmannWilliam K. MyersSimon AldridgeNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-7 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Ying Kai Loh
Petra Vasko
Caitilín McManus
Andreas Heilmann
William K. Myers
Simon Aldridge
A crystalline radical cation derived from Thiele’s hydrocarbon with redox range beyond 1 V
description Organic molecules that can access various redox states have potential applications in electronics, batteries, catalysis, among others. Here the authors report the preparation of an unsymmetrical organoboron analogue of Thiele’s hydrocarbon and study its one- and two-electron oxidation reactions; remarkably, the radical cation is stable over a redox range of > 1 V and can also be isolated.
format article
author Ying Kai Loh
Petra Vasko
Caitilín McManus
Andreas Heilmann
William K. Myers
Simon Aldridge
author_facet Ying Kai Loh
Petra Vasko
Caitilín McManus
Andreas Heilmann
William K. Myers
Simon Aldridge
author_sort Ying Kai Loh
title A crystalline radical cation derived from Thiele’s hydrocarbon with redox range beyond 1 V
title_short A crystalline radical cation derived from Thiele’s hydrocarbon with redox range beyond 1 V
title_full A crystalline radical cation derived from Thiele’s hydrocarbon with redox range beyond 1 V
title_fullStr A crystalline radical cation derived from Thiele’s hydrocarbon with redox range beyond 1 V
title_full_unstemmed A crystalline radical cation derived from Thiele’s hydrocarbon with redox range beyond 1 V
title_sort crystalline radical cation derived from thiele’s hydrocarbon with redox range beyond 1 v
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/8ac58dd707a345c69481b8094024f506
work_keys_str_mv AT yingkailoh acrystallineradicalcationderivedfromthieleshydrocarbonwithredoxrangebeyond1v
AT petravasko acrystallineradicalcationderivedfromthieleshydrocarbonwithredoxrangebeyond1v
AT caitilinmcmanus acrystallineradicalcationderivedfromthieleshydrocarbonwithredoxrangebeyond1v
AT andreasheilmann acrystallineradicalcationderivedfromthieleshydrocarbonwithredoxrangebeyond1v
AT williamkmyers acrystallineradicalcationderivedfromthieleshydrocarbonwithredoxrangebeyond1v
AT simonaldridge acrystallineradicalcationderivedfromthieleshydrocarbonwithredoxrangebeyond1v
AT yingkailoh crystallineradicalcationderivedfromthieleshydrocarbonwithredoxrangebeyond1v
AT petravasko crystallineradicalcationderivedfromthieleshydrocarbonwithredoxrangebeyond1v
AT caitilinmcmanus crystallineradicalcationderivedfromthieleshydrocarbonwithredoxrangebeyond1v
AT andreasheilmann crystallineradicalcationderivedfromthieleshydrocarbonwithredoxrangebeyond1v
AT williamkmyers crystallineradicalcationderivedfromthieleshydrocarbonwithredoxrangebeyond1v
AT simonaldridge crystallineradicalcationderivedfromthieleshydrocarbonwithredoxrangebeyond1v
_version_ 1718372027997356032

Ejemplares similares