Perspectives on the Influence of Crystal Size and Morphology on the Properties of Porous Framework Materials

Miniaturization is a key aspect of materials science. Owing to the increase in quality experimental and computational tools available to researchers, it has become clear that the crystal size and morphology of porous framework materials, including metal-organic frameworks and covalent organic framew...

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Autores principales:	Claire L. Hobday, Simon Krause, Sven M. J. Rogge, Jack D. Evans, Hana Bunzen
Formato:	article
Lenguaje:	EN
Publicado:	Frontiers Media S.A. 2021
Materias:	crystal size metal-organic frameworks soft porous crystals mechanical stability adsorption molecular simulation Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/8ad2e5ce936b4e3096e4115cd663e695
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spelling	oai:doaj.org-article:8ad2e5ce936b4e3096e4115cd663e6952021-11-11T06:34:48ZPerspectives on the Influence of Crystal Size and Morphology on the Properties of Porous Framework Materials2296-264610.3389/fchem.2021.772059https://doaj.org/article/8ad2e5ce936b4e3096e4115cd663e6952021-11-01T00:00:00Zhttps://www.frontiersin.org/articles/10.3389/fchem.2021.772059/fullhttps://doaj.org/toc/2296-2646Miniaturization is a key aspect of materials science. Owing to the increase in quality experimental and computational tools available to researchers, it has become clear that the crystal size and morphology of porous framework materials, including metal-organic frameworks and covalent organic frameworks, play a vital role in defining the physicochemical behaviour of these materials. However, given the multiscale and multidisciplinary challenges associated with establishing how crystal size and morphology affect the structure and behaviour of a material–from local to global structural modifications and from static to dynamic effects–a comprehensive mechanistic understanding of size and morphology effects is missing. Herein, we provide our perspective on the current state-of-the-art of this topic, drawn from various complementary disciplines. From a fundamental point of view, we discuss how controlling the crystal size and morphology can alter the mechanical and adsorption properties of porous framework materials and how this can impact phase stability. Special attention is also given to the quest to develop new computational tools capable of modelling these multiscale effects. From a more applied point of view, given the recent progress in this research field, we highlight the importance of crystal size and morphology control in drug delivery. Moreover, we provide an outlook on how to advance each discussed field by size and morphology control, which would open new design opportunities for functional porous framework materials.Claire L. HobdaySimon KrauseSven M. J. RoggeJack D. EvansHana BunzenFrontiers Media S.A.articlecrystal sizemetal-organic frameworkssoft porous crystalsmechanical stabilityadsorptionmolecular simulationChemistryQD1-999ENFrontiers in Chemistry, Vol 9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	crystal size metal-organic frameworks soft porous crystals mechanical stability adsorption molecular simulation Chemistry QD1-999
spellingShingle	crystal size metal-organic frameworks soft porous crystals mechanical stability adsorption molecular simulation Chemistry QD1-999 Claire L. Hobday Simon Krause Sven M. J. Rogge Jack D. Evans Hana Bunzen Perspectives on the Influence of Crystal Size and Morphology on the Properties of Porous Framework Materials
description	Miniaturization is a key aspect of materials science. Owing to the increase in quality experimental and computational tools available to researchers, it has become clear that the crystal size and morphology of porous framework materials, including metal-organic frameworks and covalent organic frameworks, play a vital role in defining the physicochemical behaviour of these materials. However, given the multiscale and multidisciplinary challenges associated with establishing how crystal size and morphology affect the structure and behaviour of a material–from local to global structural modifications and from static to dynamic effects–a comprehensive mechanistic understanding of size and morphology effects is missing. Herein, we provide our perspective on the current state-of-the-art of this topic, drawn from various complementary disciplines. From a fundamental point of view, we discuss how controlling the crystal size and morphology can alter the mechanical and adsorption properties of porous framework materials and how this can impact phase stability. Special attention is also given to the quest to develop new computational tools capable of modelling these multiscale effects. From a more applied point of view, given the recent progress in this research field, we highlight the importance of crystal size and morphology control in drug delivery. Moreover, we provide an outlook on how to advance each discussed field by size and morphology control, which would open new design opportunities for functional porous framework materials.
format	article
author	Claire L. Hobday Simon Krause Sven M. J. Rogge Jack D. Evans Hana Bunzen
author_facet	Claire L. Hobday Simon Krause Sven M. J. Rogge Jack D. Evans Hana Bunzen
author_sort	Claire L. Hobday
title	Perspectives on the Influence of Crystal Size and Morphology on the Properties of Porous Framework Materials
title_short	Perspectives on the Influence of Crystal Size and Morphology on the Properties of Porous Framework Materials
title_full	Perspectives on the Influence of Crystal Size and Morphology on the Properties of Porous Framework Materials
title_fullStr	Perspectives on the Influence of Crystal Size and Morphology on the Properties of Porous Framework Materials
title_full_unstemmed	Perspectives on the Influence of Crystal Size and Morphology on the Properties of Porous Framework Materials
title_sort	perspectives on the influence of crystal size and morphology on the properties of porous framework materials
publisher	Frontiers Media S.A.
publishDate	2021
url	https://doaj.org/article/8ad2e5ce936b4e3096e4115cd663e695
work_keys_str_mv	AT clairelhobday perspectivesontheinfluenceofcrystalsizeandmorphologyonthepropertiesofporousframeworkmaterials AT simonkrause perspectivesontheinfluenceofcrystalsizeandmorphologyonthepropertiesofporousframeworkmaterials AT svenmjrogge perspectivesontheinfluenceofcrystalsizeandmorphologyonthepropertiesofporousframeworkmaterials AT jackdevans perspectivesontheinfluenceofcrystalsizeandmorphologyonthepropertiesofporousframeworkmaterials AT hanabunzen perspectivesontheinfluenceofcrystalsizeandmorphologyonthepropertiesofporousframeworkmaterials
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Perspectives on the Influence of Crystal Size and Morphology on the Properties of Porous Framework Materials

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