Synthesis and structure of condensation product of dimethylglyoxime on gold matri

Complex of gold of the composition [AuL(NO2)] (1), where HL is a new tridentate ligand obtained by the condensation of two dimethylglyoxime (H2DMG) molecules on the matrix of the gold ion, was synthesized and characterized by X-ray structural analysis. It was shown that in the system H[AuCl4] ....

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Autores principales:	Bouroş, Pavlina, Simonov, Iurii, Bologa, Olga, Lipkowski, Janusz
Formato:	article
Lenguaje:	EN
Publicado:	D.Ghitu Institute of Electronic Engineering and Nanotechnologies 2008
Materias:	Physics QC1-999 Electronics TK7800-8360
Acceso en línea:	https://doaj.org/article/8ad40933fff14d9f88938b06f43b65fe
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spelling	oai:doaj.org-article:8ad40933fff14d9f88938b06f43b65fe2021-11-21T12:06:51ZSynthesis and structure of condensation product of dimethylglyoxime on gold matri 2537-63651810-648Xhttps://doaj.org/article/8ad40933fff14d9f88938b06f43b65fe2008-07-01T00:00:00Zhttps://mjps.nanotech.md/archive/2008/article/3924https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365Complex of gold of the composition [AuL(NO2)] (1), where HL is a new tridentate ligand obtained by the condensation of two dimethylglyoxime (H2DMG) molecules on the matrix of the gold ion, was synthesized and characterized by X-ray structural analysis. It was shown that in the system H[AuCl4] . 4Н2О H2DMG Py, depending on pH of the reaction medium and sequence of addition of components, the final products have unexpected compositions ([AuIII (DMG)ClPy], [AuCl2Py2][AuCl4] . 2[AuCl3Py] or [AuII L(NO2)]). Molecular complex 1 is sustained by the Au....Au…Au intermolecular nteractions. Bouroş, PavlinaSimonov, IuriiBologa, OlgaLipkowski, JanuszD.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 7, Iss 3, Pp 382-388 (2008)
institution	DOAJ
collection	DOAJ
language	EN
topic	Physics QC1-999 Electronics TK7800-8360
spellingShingle	Physics QC1-999 Electronics TK7800-8360 Bouroş, Pavlina Simonov, Iurii Bologa, Olga Lipkowski, Janusz Synthesis and structure of condensation product of dimethylglyoxime on gold matri
description	Complex of gold of the composition [AuL(NO2)] (1), where HL is a new tridentate ligand obtained by the condensation of two dimethylglyoxime (H2DMG) molecules on the matrix of the gold ion, was synthesized and characterized by X-ray structural analysis. It was shown that in the system H[AuCl4] . 4Н2О H2DMG Py, depending on pH of the reaction medium and sequence of addition of components, the final products have unexpected compositions ([AuIII (DMG)ClPy], [AuCl2Py2][AuCl4] . 2[AuCl3Py] or [AuII L(NO2)]). Molecular complex 1 is sustained by the Au....Au…Au intermolecular nteractions.
format	article
author	Bouroş, Pavlina Simonov, Iurii Bologa, Olga Lipkowski, Janusz
author_facet	Bouroş, Pavlina Simonov, Iurii Bologa, Olga Lipkowski, Janusz
author_sort	Bouroş, Pavlina
title	Synthesis and structure of condensation product of dimethylglyoxime on gold matri
title_short	Synthesis and structure of condensation product of dimethylglyoxime on gold matri
title_full	Synthesis and structure of condensation product of dimethylglyoxime on gold matri
title_fullStr	Synthesis and structure of condensation product of dimethylglyoxime on gold matri
title_full_unstemmed	Synthesis and structure of condensation product of dimethylglyoxime on gold matri
title_sort	synthesis and structure of condensation product of dimethylglyoxime on gold matri
publisher	D.Ghitu Institute of Electronic Engineering and Nanotechnologies
publishDate	2008
url	https://doaj.org/article/8ad40933fff14d9f88938b06f43b65fe
work_keys_str_mv	AT bourospavlina synthesisandstructureofcondensationproductofdimethylglyoximeongoldmatri AT simonoviurii synthesisandstructureofcondensationproductofdimethylglyoximeongoldmatri AT bologaolga synthesisandstructureofcondensationproductofdimethylglyoximeongoldmatri AT lipkowskijanusz synthesisandstructureofcondensationproductofdimethylglyoximeongoldmatri
_version_	1718419198122655744

Synthesis and structure of condensation product of dimethylglyoxime on gold matri

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