Fabrication of poly(vinylidene fluoride) film and application to printing technology

Poly(vinylidene fluoride) (PVDF) has four crystalline structures (α, β, γ and δ phase structures) in solid state. Only α-phase structure shows no crystal dipole, but this phase structure is converted easily into other phase structures according to some schemes. Generally, PVDF is given uniaxial stre...

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Autores principales: Atsuki SHIRATORI, Noriyasu YAMADA, Akihiro NISHIOKA, Go MURASAWA
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Lenguaje:EN
Publicado: The Japan Society of Mechanical Engineers 2016
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Acceso en línea:https://doaj.org/article/8b30dd972d434b11a00e243c5ac5f1ad
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spelling oai:doaj.org-article:8b30dd972d434b11a00e243c5ac5f1ad2021-11-26T06:35:12ZFabrication of poly(vinylidene fluoride) film and application to printing technology2187-974510.1299/mej.14-00405https://doaj.org/article/8b30dd972d434b11a00e243c5ac5f1ad2016-01-01T00:00:00Zhttps://www.jstage.jst.go.jp/article/mej/3/1/3_14-00405/_pdf/-char/enhttps://doaj.org/toc/2187-9745Poly(vinylidene fluoride) (PVDF) has four crystalline structures (α, β, γ and δ phase structures) in solid state. Only α-phase structure shows no crystal dipole, but this phase structure is converted easily into other phase structures according to some schemes. Generally, PVDF is given uniaxial stretch and polarization processes in order to convert into β-phase structure before sensor and actuator film use. However, we recently found a novel method in which PVDF film structure became β-phase without mechanical deformation processes. Furthermore, this technique enables us to apply printing technology, and realize the creation of free-form 3D sensor and actuators. No one can see free-form PVDF printer up to the present. The aim of the present study is to evaluate the crystalline structure and cross-sectional profile for PVDF films fabricated by present method. In addition, a novel PVDF printer, which can draw free-form 2D PVDF film, is developed on the basis of experimental results. First, a PVDF film is fabricated by dropping and drying a PVDF solution droplet. In this film fabrication, some PVDF solution droplets are prepared by changing the combination of the PVDF solution drop quantity and PVDF concentration in solution. Second, their PVDF crystalline structure is analyzed with an X-ray diffraction device. Then, PVDF film cross-sectional profile is measured with 3D shape measurement machine. In addition, the PVDF crystallinity degree is measured by differential scanning calorimetry. Third, a novel PVDF printer system is developed on the basis of present fabrication method. Then, the outline of free-draw 2D picture is printed as PVDF point drawing film on a 12mm×12mm glass plate, and the accuracy is investigated for printed PVDF films.Atsuki SHIRATORINoriyasu YAMADAAkihiro NISHIOKAGo MURASAWAThe Japan Society of Mechanical Engineersarticlepoly(vinylidene fluoride)crystalline structurepvdf solution dropletsolution concentrationdroplet quantityx-ray analysiscross-sectional profile measurementdifferential scanning calorimetryMechanical engineering and machineryTJ1-1570ENMechanical Engineering Journal, Vol 3, Iss 1, Pp 14-00405-14-00405 (2016)
institution DOAJ
collection DOAJ
language EN
topic poly(vinylidene fluoride)
crystalline structure
pvdf solution droplet
solution concentration
droplet quantity
x-ray analysis
cross-sectional profile measurement
differential scanning calorimetry
Mechanical engineering and machinery
TJ1-1570
spellingShingle poly(vinylidene fluoride)
crystalline structure
pvdf solution droplet
solution concentration
droplet quantity
x-ray analysis
cross-sectional profile measurement
differential scanning calorimetry
Mechanical engineering and machinery
TJ1-1570
Atsuki SHIRATORI
Noriyasu YAMADA
Akihiro NISHIOKA
Go MURASAWA
Fabrication of poly(vinylidene fluoride) film and application to printing technology
description Poly(vinylidene fluoride) (PVDF) has four crystalline structures (α, β, γ and δ phase structures) in solid state. Only α-phase structure shows no crystal dipole, but this phase structure is converted easily into other phase structures according to some schemes. Generally, PVDF is given uniaxial stretch and polarization processes in order to convert into β-phase structure before sensor and actuator film use. However, we recently found a novel method in which PVDF film structure became β-phase without mechanical deformation processes. Furthermore, this technique enables us to apply printing technology, and realize the creation of free-form 3D sensor and actuators. No one can see free-form PVDF printer up to the present. The aim of the present study is to evaluate the crystalline structure and cross-sectional profile for PVDF films fabricated by present method. In addition, a novel PVDF printer, which can draw free-form 2D PVDF film, is developed on the basis of experimental results. First, a PVDF film is fabricated by dropping and drying a PVDF solution droplet. In this film fabrication, some PVDF solution droplets are prepared by changing the combination of the PVDF solution drop quantity and PVDF concentration in solution. Second, their PVDF crystalline structure is analyzed with an X-ray diffraction device. Then, PVDF film cross-sectional profile is measured with 3D shape measurement machine. In addition, the PVDF crystallinity degree is measured by differential scanning calorimetry. Third, a novel PVDF printer system is developed on the basis of present fabrication method. Then, the outline of free-draw 2D picture is printed as PVDF point drawing film on a 12mm×12mm glass plate, and the accuracy is investigated for printed PVDF films.
format article
author Atsuki SHIRATORI
Noriyasu YAMADA
Akihiro NISHIOKA
Go MURASAWA
author_facet Atsuki SHIRATORI
Noriyasu YAMADA
Akihiro NISHIOKA
Go MURASAWA
author_sort Atsuki SHIRATORI
title Fabrication of poly(vinylidene fluoride) film and application to printing technology
title_short Fabrication of poly(vinylidene fluoride) film and application to printing technology
title_full Fabrication of poly(vinylidene fluoride) film and application to printing technology
title_fullStr Fabrication of poly(vinylidene fluoride) film and application to printing technology
title_full_unstemmed Fabrication of poly(vinylidene fluoride) film and application to printing technology
title_sort fabrication of poly(vinylidene fluoride) film and application to printing technology
publisher The Japan Society of Mechanical Engineers
publishDate 2016
url https://doaj.org/article/8b30dd972d434b11a00e243c5ac5f1ad
work_keys_str_mv AT atsukishiratori fabricationofpolyvinylidenefluoridefilmandapplicationtoprintingtechnology
AT noriyasuyamada fabricationofpolyvinylidenefluoridefilmandapplicationtoprintingtechnology
AT akihironishioka fabricationofpolyvinylidenefluoridefilmandapplicationtoprintingtechnology
AT gomurasawa fabricationofpolyvinylidenefluoridefilmandapplicationtoprintingtechnology
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