Dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates

Synthesis of valuable polyene molecules under mild conditions and with good functional groups tolerance is of paramount importance. Here, the authors show the versatile copper-catalyzed successive dehydrogenation of a variety of organic substrates affording highly conjugated unsaturated products.

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Autores principales:	Yaping Shang, Xiaoming Jie, Krishna Jonnada, Syeda Nahid Zafar, Weiping Su
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/8b31f860c29e4fcca0aed5e8acbe8a7a
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spelling	oai:doaj.org-article:8b31f860c29e4fcca0aed5e8acbe8a7a2021-12-02T17:06:07ZDehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates10.1038/s41467-017-02381-82041-1723https://doaj.org/article/8b31f860c29e4fcca0aed5e8acbe8a7a2017-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-02381-8https://doaj.org/toc/2041-1723Synthesis of valuable polyene molecules under mild conditions and with good functional groups tolerance is of paramount importance. Here, the authors show the versatile copper-catalyzed successive dehydrogenation of a variety of organic substrates affording highly conjugated unsaturated products.Yaping ShangXiaoming JieKrishna JonnadaSyeda Nahid ZafarWeiping SuNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-8 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yaping Shang Xiaoming Jie Krishna Jonnada Syeda Nahid Zafar Weiping Su Dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates
description	Synthesis of valuable polyene molecules under mild conditions and with good functional groups tolerance is of paramount importance. Here, the authors show the versatile copper-catalyzed successive dehydrogenation of a variety of organic substrates affording highly conjugated unsaturated products.
format	article
author	Yaping Shang Xiaoming Jie Krishna Jonnada Syeda Nahid Zafar Weiping Su
author_facet	Yaping Shang Xiaoming Jie Krishna Jonnada Syeda Nahid Zafar Weiping Su
author_sort	Yaping Shang
title	Dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates
title_short	Dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates
title_full	Dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates
title_fullStr	Dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates
title_full_unstemmed	Dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates
title_sort	dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/8b31f860c29e4fcca0aed5e8acbe8a7a
work_keys_str_mv	AT yapingshang dehydrogenativedesaturationrelayviaformationofmulticenterstabilizedradicalintermediates AT xiaomingjie dehydrogenativedesaturationrelayviaformationofmulticenterstabilizedradicalintermediates AT krishnajonnada dehydrogenativedesaturationrelayviaformationofmulticenterstabilizedradicalintermediates AT syedanahidzafar dehydrogenativedesaturationrelayviaformationofmulticenterstabilizedradicalintermediates AT weipingsu dehydrogenativedesaturationrelayviaformationofmulticenterstabilizedradicalintermediates
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Dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates

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