Accumulating the hydride state in the catalytic cycle of [FeFe]-hydrogenases

Of the four intermediates in the catalytic cycle of [FeFe]-hydrogenases, the hydride state still has eluded characterization. Here, the authors shift the reaction equilibrium for three hydrogenases and enrich the hydride-bound species, characterizing them using a real-time IR spectroscopic technique...

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Autores principales:	Martin Winkler, Moritz Senger, Jifu Duan, Julian Esselborn, Florian Wittkamp, Eckhard Hofmann, Ulf-Peter Apfel, Sven Timo Stripp, Thomas Happe
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/8b8423f5ac15415e844771a44e6de8f5
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spelling	oai:doaj.org-article:8b8423f5ac15415e844771a44e6de8f52021-12-02T15:38:37ZAccumulating the hydride state in the catalytic cycle of [FeFe]-hydrogenases10.1038/ncomms161152041-1723https://doaj.org/article/8b8423f5ac15415e844771a44e6de8f52017-07-01T00:00:00Zhttps://doi.org/10.1038/ncomms16115https://doaj.org/toc/2041-1723Of the four intermediates in the catalytic cycle of [FeFe]-hydrogenases, the hydride state still has eluded characterization. Here, the authors shift the reaction equilibrium for three hydrogenases and enrich the hydride-bound species, characterizing them using a real-time IR spectroscopic technique.Martin WinklerMoritz SengerJifu DuanJulian EsselbornFlorian WittkampEckhard HofmannUlf-Peter ApfelSven Timo StrippThomas HappeNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Martin Winkler Moritz Senger Jifu Duan Julian Esselborn Florian Wittkamp Eckhard Hofmann Ulf-Peter Apfel Sven Timo Stripp Thomas Happe Accumulating the hydride state in the catalytic cycle of [FeFe]-hydrogenases
description	Of the four intermediates in the catalytic cycle of [FeFe]-hydrogenases, the hydride state still has eluded characterization. Here, the authors shift the reaction equilibrium for three hydrogenases and enrich the hydride-bound species, characterizing them using a real-time IR spectroscopic technique.
format	article
author	Martin Winkler Moritz Senger Jifu Duan Julian Esselborn Florian Wittkamp Eckhard Hofmann Ulf-Peter Apfel Sven Timo Stripp Thomas Happe
author_facet	Martin Winkler Moritz Senger Jifu Duan Julian Esselborn Florian Wittkamp Eckhard Hofmann Ulf-Peter Apfel Sven Timo Stripp Thomas Happe
author_sort	Martin Winkler
title	Accumulating the hydride state in the catalytic cycle of [FeFe]-hydrogenases
title_short	Accumulating the hydride state in the catalytic cycle of [FeFe]-hydrogenases
title_full	Accumulating the hydride state in the catalytic cycle of [FeFe]-hydrogenases
title_fullStr	Accumulating the hydride state in the catalytic cycle of [FeFe]-hydrogenases
title_full_unstemmed	Accumulating the hydride state in the catalytic cycle of [FeFe]-hydrogenases
title_sort	accumulating the hydride state in the catalytic cycle of [fefe]-hydrogenases
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/8b8423f5ac15415e844771a44e6de8f5
work_keys_str_mv	AT martinwinkler accumulatingthehydridestateinthecatalyticcycleoffefehydrogenases AT moritzsenger accumulatingthehydridestateinthecatalyticcycleoffefehydrogenases AT jifuduan accumulatingthehydridestateinthecatalyticcycleoffefehydrogenases AT julianesselborn accumulatingthehydridestateinthecatalyticcycleoffefehydrogenases AT florianwittkamp accumulatingthehydridestateinthecatalyticcycleoffefehydrogenases AT eckhardhofmann accumulatingthehydridestateinthecatalyticcycleoffefehydrogenases AT ulfpeterapfel accumulatingthehydridestateinthecatalyticcycleoffefehydrogenases AT sventimostripp accumulatingthehydridestateinthecatalyticcycleoffefehydrogenases AT thomashappe accumulatingthehydridestateinthecatalyticcycleoffefehydrogenases
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Accumulating the hydride state in the catalytic cycle of [FeFe]-hydrogenases

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