Copper-azide nanoparticle: a ‘catalyst-cum-reagent’ for the designing of 5-alkynyl 1,4-disubstituted triazoles

Abstract A single pot, wet chemical route has been applied for the synthesis of polymer supported copper azide, CuN3, nanoparticles (CANP). The hybrid system was used as ‘catalyst-cum-reagent’ for the azide-alkyne cyclo-addition reaction to construct triazole molecules using substituted benzyl bromi...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Debkumar Nandi, Venkata K. Perla, Sarit K. Ghosh, Charmaine Arderne, Kaushik Mallick
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/8c62f8d1afc54691b72be3226365907e
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:8c62f8d1afc54691b72be3226365907e
record_format	dspace
spelling	oai:doaj.org-article:8c62f8d1afc54691b72be3226365907e2021-12-02T18:36:14ZCopper-azide nanoparticle: a ‘catalyst-cum-reagent’ for the designing of 5-alkynyl 1,4-disubstituted triazoles10.1038/s41598-020-74018-82045-2322https://doaj.org/article/8c62f8d1afc54691b72be3226365907e2020-10-01T00:00:00Zhttps://doi.org/10.1038/s41598-020-74018-8https://doaj.org/toc/2045-2322Abstract A single pot, wet chemical route has been applied for the synthesis of polymer supported copper azide, CuN3, nanoparticles (CANP). The hybrid system was used as ‘catalyst-cum-reagent’ for the azide-alkyne cyclo-addition reaction to construct triazole molecules using substituted benzyl bromide and terminal alkyne. The electron donating group containing terminal alkyne produced 5-alkynyl 1,4-disubstituded triazole product whereas for alkyne molecule with terminal electron withdrawing group facilitate the formation of 1,4-disubstituted triazole molecule.Debkumar NandiVenkata K. PerlaSarit K. GhoshCharmaine ArderneKaushik MallickNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 10, Iss 1, Pp 1-10 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Debkumar Nandi Venkata K. Perla Sarit K. Ghosh Charmaine Arderne Kaushik Mallick Copper-azide nanoparticle: a ‘catalyst-cum-reagent’ for the designing of 5-alkynyl 1,4-disubstituted triazoles
description	Abstract A single pot, wet chemical route has been applied for the synthesis of polymer supported copper azide, CuN3, nanoparticles (CANP). The hybrid system was used as ‘catalyst-cum-reagent’ for the azide-alkyne cyclo-addition reaction to construct triazole molecules using substituted benzyl bromide and terminal alkyne. The electron donating group containing terminal alkyne produced 5-alkynyl 1,4-disubstituded triazole product whereas for alkyne molecule with terminal electron withdrawing group facilitate the formation of 1,4-disubstituted triazole molecule.
format	article
author	Debkumar Nandi Venkata K. Perla Sarit K. Ghosh Charmaine Arderne Kaushik Mallick
author_facet	Debkumar Nandi Venkata K. Perla Sarit K. Ghosh Charmaine Arderne Kaushik Mallick
author_sort	Debkumar Nandi
title	Copper-azide nanoparticle: a ‘catalyst-cum-reagent’ for the designing of 5-alkynyl 1,4-disubstituted triazoles
title_short	Copper-azide nanoparticle: a ‘catalyst-cum-reagent’ for the designing of 5-alkynyl 1,4-disubstituted triazoles
title_full	Copper-azide nanoparticle: a ‘catalyst-cum-reagent’ for the designing of 5-alkynyl 1,4-disubstituted triazoles
title_fullStr	Copper-azide nanoparticle: a ‘catalyst-cum-reagent’ for the designing of 5-alkynyl 1,4-disubstituted triazoles
title_full_unstemmed	Copper-azide nanoparticle: a ‘catalyst-cum-reagent’ for the designing of 5-alkynyl 1,4-disubstituted triazoles
title_sort	copper-azide nanoparticle: a ‘catalyst-cum-reagent’ for the designing of 5-alkynyl 1,4-disubstituted triazoles
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/8c62f8d1afc54691b72be3226365907e
work_keys_str_mv	AT debkumarnandi copperazidenanoparticleacatalystcumreagentforthedesigningof5alkynyl14disubstitutedtriazoles AT venkatakperla copperazidenanoparticleacatalystcumreagentforthedesigningof5alkynyl14disubstitutedtriazoles AT saritkghosh copperazidenanoparticleacatalystcumreagentforthedesigningof5alkynyl14disubstitutedtriazoles AT charmainearderne copperazidenanoparticleacatalystcumreagentforthedesigningof5alkynyl14disubstitutedtriazoles AT kaushikmallick copperazidenanoparticleacatalystcumreagentforthedesigningof5alkynyl14disubstitutedtriazoles
_version_	1718377873884053504

Copper-azide nanoparticle: a ‘catalyst-cum-reagent’ for the designing of 5-alkynyl 1,4-disubstituted triazoles

Ejemplares similares