Supramolecular copolymerization driven by integrative self-sorting of hydrogen-bonded rosettes

Unlike natural supramolecular polymers, artificial counterparts do not have molecular recognition processes to preorganize the supramolecular complexes before final assembly. Here, the authors show supramolecular copolymerization driven by integrative self-sorting of two different monomers into disc...

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Autores principales: Keisuke Aratsu, Rika Takeya, Brian R. Pauw, Martin J. Hollamby, Yuichi Kitamoto, Nobutaka Shimizu, Hideaki Takagi, Rie Haruki, Shin-ichi Adachi, Shiki Yagai
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/8c84589af5cc42c8a83f88eaca1994ea
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Sumario:Unlike natural supramolecular polymers, artificial counterparts do not have molecular recognition processes to preorganize the supramolecular complexes before final assembly. Here, the authors show supramolecular copolymerization driven by integrative self-sorting of two different monomers into discrete six-membered supramolecular complexes (rosettes).