Development of Capacitive-Type Sensors by Electrochemical Anodization: Humidity and Touch Sensing Applications

This work describes the development of a capacitive-type sensor created from nanoporous anodic aluminium oxide (NP-AAO) prepared by the one-step anodization method conducted in potentiostatic mode and performed in a low-cost homemade system. A series of samples were prepared via an anodization campa...

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Autores principales: Joaquim O. Carneiro, Artur Ribeiro, Filipe Miranda, Iran Rocha Segundo, Salmon Landi, Vasco Teixeira, Manuel F. M. Costa
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:8cfdbbd78dad43039be1f8ddaa7aa4802021-11-11T19:16:00ZDevelopment of Capacitive-Type Sensors by Electrochemical Anodization: Humidity and Touch Sensing Applications10.3390/s212173171424-8220https://doaj.org/article/8cfdbbd78dad43039be1f8ddaa7aa4802021-11-01T00:00:00Zhttps://www.mdpi.com/1424-8220/21/21/7317https://doaj.org/toc/1424-8220This work describes the development of a capacitive-type sensor created from nanoporous anodic aluminium oxide (NP-AAO) prepared by the one-step anodization method conducted in potentiostatic mode and performed in a low-cost homemade system. A series of samples were prepared via an anodization campaign carried out on different acid electrolytes, in which the anodization parameters were adjusted to investigate the effect of pore size and porosity on the capacitive sensing performance. Two sensor test cases are investigated. The first case explores the use of highly uniform NP-AAO structures for humidity sensing applications while the second analyses the use of NP-AAO as a capacitive touch sensor for biological applications, namely, to detect the presence of small “objects” such as bacterial colonies of <i>Escherichia Coli.</i> A mathematical model based on equivalent electrical circuits was developed to evaluate the effect of humidity condensation (inside the pores) on the sensor capacitance and also to estimate the capacitance change of the sensor due to pore blocking by the presence of a certain number of bacterial microorganisms. Regarding the humidity sensing test cases, it was found that the sensitivity of the sensor fabricated in a phosphoric acid solution reaches up to 39 (pF/RH%), which is almost three times higher than the sensor fabricated in oxalic acid and about eight times higher than the sensor fabricated in sulfuric acid. Its improved sensitivity is explained in terms of the pore size effect on the mean free path and the loss of Brownian energy of the water vapour molecules. Concerning the touch sensing test case, it is demonstrated that the NP-AAO structures can be used as capacitive touch sensors because the magnitude of the capacitance change directly depends on the number of bacteria that cover the nanopores; the fraction of the electrode area activated by bacterial pore blocking is about 4.4% and 30.2% for B1 (<i>E. Coli</i> OD<sub>600nm</sub> = 0.1) and B2 (<i>E. Coli</i> OD<sub>600nm</sub> = 1) sensors, respectively.Joaquim O. CarneiroArtur RibeiroFilipe MirandaIran Rocha SegundoSalmon LandiVasco TeixeiraManuel F. M. CostaMDPI AGarticlecapacitive-type sensorsensitivityanodizationnanoporous anodic aluminaChemical technologyTP1-1185ENSensors, Vol 21, Iss 7317, p 7317 (2021)
institution DOAJ
collection DOAJ
language EN
topic capacitive-type sensor
sensitivity
anodization
nanoporous anodic alumina
Chemical technology
TP1-1185
spellingShingle capacitive-type sensor
sensitivity
anodization
nanoporous anodic alumina
Chemical technology
TP1-1185
Joaquim O. Carneiro
Artur Ribeiro
Filipe Miranda
Iran Rocha Segundo
Salmon Landi
Vasco Teixeira
Manuel F. M. Costa
Development of Capacitive-Type Sensors by Electrochemical Anodization: Humidity and Touch Sensing Applications
description This work describes the development of a capacitive-type sensor created from nanoporous anodic aluminium oxide (NP-AAO) prepared by the one-step anodization method conducted in potentiostatic mode and performed in a low-cost homemade system. A series of samples were prepared via an anodization campaign carried out on different acid electrolytes, in which the anodization parameters were adjusted to investigate the effect of pore size and porosity on the capacitive sensing performance. Two sensor test cases are investigated. The first case explores the use of highly uniform NP-AAO structures for humidity sensing applications while the second analyses the use of NP-AAO as a capacitive touch sensor for biological applications, namely, to detect the presence of small “objects” such as bacterial colonies of <i>Escherichia Coli.</i> A mathematical model based on equivalent electrical circuits was developed to evaluate the effect of humidity condensation (inside the pores) on the sensor capacitance and also to estimate the capacitance change of the sensor due to pore blocking by the presence of a certain number of bacterial microorganisms. Regarding the humidity sensing test cases, it was found that the sensitivity of the sensor fabricated in a phosphoric acid solution reaches up to 39 (pF/RH%), which is almost three times higher than the sensor fabricated in oxalic acid and about eight times higher than the sensor fabricated in sulfuric acid. Its improved sensitivity is explained in terms of the pore size effect on the mean free path and the loss of Brownian energy of the water vapour molecules. Concerning the touch sensing test case, it is demonstrated that the NP-AAO structures can be used as capacitive touch sensors because the magnitude of the capacitance change directly depends on the number of bacteria that cover the nanopores; the fraction of the electrode area activated by bacterial pore blocking is about 4.4% and 30.2% for B1 (<i>E. Coli</i> OD<sub>600nm</sub> = 0.1) and B2 (<i>E. Coli</i> OD<sub>600nm</sub> = 1) sensors, respectively.
format article
author Joaquim O. Carneiro
Artur Ribeiro
Filipe Miranda
Iran Rocha Segundo
Salmon Landi
Vasco Teixeira
Manuel F. M. Costa
author_facet Joaquim O. Carneiro
Artur Ribeiro
Filipe Miranda
Iran Rocha Segundo
Salmon Landi
Vasco Teixeira
Manuel F. M. Costa
author_sort Joaquim O. Carneiro
title Development of Capacitive-Type Sensors by Electrochemical Anodization: Humidity and Touch Sensing Applications
title_short Development of Capacitive-Type Sensors by Electrochemical Anodization: Humidity and Touch Sensing Applications
title_full Development of Capacitive-Type Sensors by Electrochemical Anodization: Humidity and Touch Sensing Applications
title_fullStr Development of Capacitive-Type Sensors by Electrochemical Anodization: Humidity and Touch Sensing Applications
title_full_unstemmed Development of Capacitive-Type Sensors by Electrochemical Anodization: Humidity and Touch Sensing Applications
title_sort development of capacitive-type sensors by electrochemical anodization: humidity and touch sensing applications
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/8cfdbbd78dad43039be1f8ddaa7aa480
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