Hydrogen radical-shuttle (HRS)-enabled photoredox synthesis of indanones via decarboxylative annulation

Hydrogen radical-shuttle (HRS)-enabled photoredox synthesis of indanones via decarboxylative annulation

Although hydrogen atom transfer is widely observed in synthetic organic chemistry, intramolecular hydrogen atom transfer between atoms separated by fewer than four bonds is kinetically slow. Here the authors show a method to form indanones, with hydrogen atoms shuttled across short distances by wate...

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Autores principales: Bo Yang, Shi-Jun Li, Yongdong Wang, Yu Lan, Shifa Zhu
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/8d0c37d1be8f49c49cf810eeffb23dc7
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spelling oai:doaj.org-article:8d0c37d1be8f49c49cf810eeffb23dc72021-12-02T14:55:15ZHydrogen radical-shuttle (HRS)-enabled photoredox synthesis of indanones via decarboxylative annulation10.1038/s41467-021-25594-42041-1723https://doaj.org/article/8d0c37d1be8f49c49cf810eeffb23dc72021-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-25594-4https://doaj.org/toc/2041-1723Although hydrogen atom transfer is widely observed in synthetic organic chemistry, intramolecular hydrogen atom transfer between atoms separated by fewer than four bonds is kinetically slow. Here the authors show a method to form indanones, with hydrogen atoms shuttled across short distances by water.Bo YangShi-Jun LiYongdong WangYu LanShifa ZhuNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-11 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Bo Yang
Shi-Jun Li
Yongdong Wang
Yu Lan
Shifa Zhu
Hydrogen radical-shuttle (HRS)-enabled photoredox synthesis of indanones via decarboxylative annulation
description Although hydrogen atom transfer is widely observed in synthetic organic chemistry, intramolecular hydrogen atom transfer between atoms separated by fewer than four bonds is kinetically slow. Here the authors show a method to form indanones, with hydrogen atoms shuttled across short distances by water.
format article
author Bo Yang
Shi-Jun Li
Yongdong Wang
Yu Lan
Shifa Zhu
author_facet Bo Yang
Shi-Jun Li
Yongdong Wang
Yu Lan
Shifa Zhu
author_sort Bo Yang
title Hydrogen radical-shuttle (HRS)-enabled photoredox synthesis of indanones via decarboxylative annulation
title_short Hydrogen radical-shuttle (HRS)-enabled photoredox synthesis of indanones via decarboxylative annulation
title_full Hydrogen radical-shuttle (HRS)-enabled photoredox synthesis of indanones via decarboxylative annulation
title_fullStr Hydrogen radical-shuttle (HRS)-enabled photoredox synthesis of indanones via decarboxylative annulation
title_full_unstemmed Hydrogen radical-shuttle (HRS)-enabled photoredox synthesis of indanones via decarboxylative annulation
title_sort hydrogen radical-shuttle (hrs)-enabled photoredox synthesis of indanones via decarboxylative annulation
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/8d0c37d1be8f49c49cf810eeffb23dc7
work_keys_str_mv AT boyang hydrogenradicalshuttlehrsenabledphotoredoxsynthesisofindanonesviadecarboxylativeannulation
AT shijunli hydrogenradicalshuttlehrsenabledphotoredoxsynthesisofindanonesviadecarboxylativeannulation
AT yongdongwang hydrogenradicalshuttlehrsenabledphotoredoxsynthesisofindanonesviadecarboxylativeannulation
AT yulan hydrogenradicalshuttlehrsenabledphotoredoxsynthesisofindanonesviadecarboxylativeannulation
AT shifazhu hydrogenradicalshuttlehrsenabledphotoredoxsynthesisofindanonesviadecarboxylativeannulation
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