Electrochemical oxidation induced intermolecular aromatic C-H imidation

The dehydrogenative C-H/N-H cross-coupling serves to install nitrogen functionalities into arenes with the highest atom economy. Here, the authors report an electrochemical cross-coupling between aromatics and sulfonimides through an N-radical addition pathway under oxidant- and catalyst-free condit...

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Autores principales: Xia Hu, Guoting Zhang, Lei Nie, Taige Kong, Aiwen Lei
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/8d2b052c74514404a7e580dafa48794f
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Sumario:The dehydrogenative C-H/N-H cross-coupling serves to install nitrogen functionalities into arenes with the highest atom economy. Here, the authors report an electrochemical cross-coupling between aromatics and sulfonimides through an N-radical addition pathway under oxidant- and catalyst-free conditions.