Electrochemical oxidation induced intermolecular aromatic C-H imidation
The dehydrogenative C-H/N-H cross-coupling serves to install nitrogen functionalities into arenes with the highest atom economy. Here, the authors report an electrochemical cross-coupling between aromatics and sulfonimides through an N-radical addition pathway under oxidant- and catalyst-free condit...
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Nature Portfolio
2019
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oai:doaj.org-article:8d2b052c74514404a7e580dafa48794f2021-12-02T16:57:54ZElectrochemical oxidation induced intermolecular aromatic C-H imidation10.1038/s41467-019-13524-42041-1723https://doaj.org/article/8d2b052c74514404a7e580dafa48794f2019-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-13524-4https://doaj.org/toc/2041-1723The dehydrogenative C-H/N-H cross-coupling serves to install nitrogen functionalities into arenes with the highest atom economy. Here, the authors report an electrochemical cross-coupling between aromatics and sulfonimides through an N-radical addition pathway under oxidant- and catalyst-free conditions.Xia HuGuoting ZhangLei NieTaige KongAiwen LeiNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019) |
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Science Q Xia Hu Guoting Zhang Lei Nie Taige Kong Aiwen Lei Electrochemical oxidation induced intermolecular aromatic C-H imidation |
description |
The dehydrogenative C-H/N-H cross-coupling serves to install nitrogen functionalities into arenes with the highest atom economy. Here, the authors report an electrochemical cross-coupling between aromatics and sulfonimides through an N-radical addition pathway under oxidant- and catalyst-free conditions. |
format |
article |
author |
Xia Hu Guoting Zhang Lei Nie Taige Kong Aiwen Lei |
author_facet |
Xia Hu Guoting Zhang Lei Nie Taige Kong Aiwen Lei |
author_sort |
Xia Hu |
title |
Electrochemical oxidation induced intermolecular aromatic C-H imidation |
title_short |
Electrochemical oxidation induced intermolecular aromatic C-H imidation |
title_full |
Electrochemical oxidation induced intermolecular aromatic C-H imidation |
title_fullStr |
Electrochemical oxidation induced intermolecular aromatic C-H imidation |
title_full_unstemmed |
Electrochemical oxidation induced intermolecular aromatic C-H imidation |
title_sort |
electrochemical oxidation induced intermolecular aromatic c-h imidation |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/8d2b052c74514404a7e580dafa48794f |
work_keys_str_mv |
AT xiahu electrochemicaloxidationinducedintermoleculararomaticchimidation AT guotingzhang electrochemicaloxidationinducedintermoleculararomaticchimidation AT leinie electrochemicaloxidationinducedintermoleculararomaticchimidation AT taigekong electrochemicaloxidationinducedintermoleculararomaticchimidation AT aiwenlei electrochemicaloxidationinducedintermoleculararomaticchimidation |
_version_ |
1718382457745571840 |