Rheological and Technological Aspects in Designing the Properties of Shear Thickening Fluids

This work focuses on shear thickening fluids (STFs) as ceramic–polymer composites with outstanding protective properties. The investigation aims to determine the influence of raw material parameters on the functional properties of STFs. The following analyses were used to characterize both the raw m...

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Autores principales: Radosław Żurowski, Paweł Falkowski, Justyna Zygmuntowicz, Mikołaj Szafran
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Lenguaje:EN
Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:8df8ad06319f49be98714590c9640d862021-11-11T18:08:24ZRheological and Technological Aspects in Designing the Properties of Shear Thickening Fluids10.3390/ma142165851996-1944https://doaj.org/article/8df8ad06319f49be98714590c9640d862021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1944/14/21/6585https://doaj.org/toc/1996-1944This work focuses on shear thickening fluids (STFs) as ceramic–polymer composites with outstanding protective properties. The investigation aims to determine the influence of raw material parameters on the functional properties of STFs. The following analyses were used to characterize both the raw materials and the STFs: scanning electron microscopy, dynamic light scattering, matrix-assisted laser desorption/ionization time-of-flight, chemical sorption analysis, rheological analysis, and kinetic energy dissipation tests. It was confirmed that the morphology of the solid particles plays a key role in designing the rheological and protective properties of STFs. In the case of irregular silica, shear thickening properties can be obtained from a solid content of 12.5 vol.%. For spherical silica, the limit for achieving shear thickening behavior is 40 vol.%. The viscosity curve analysis allowed for the introduction of a new parameter defining the functional properties of STFs: the technological critical shear rate. The ability of STFs to dissipate kinetic energy was determined using a unique device that allows pure fluids to be tested without prior encapsulation. Because of this, it was possible to observe even slight differences in the protective properties between different STFs, which has not been possible so far. During tests with an energy of 50 J, the dissipation factor was over 96%.Radosław ŻurowskiPaweł FalkowskiJustyna ZygmuntowiczMikołaj SzafranMDPI AGarticleceramic–polymer compositesintelligent materialsprotective propertiesrheological propertiesshear thickening fluidsTechnologyTElectrical engineering. Electronics. Nuclear engineeringTK1-9971Engineering (General). Civil engineering (General)TA1-2040MicroscopyQH201-278.5Descriptive and experimental mechanicsQC120-168.85ENMaterials, Vol 14, Iss 6585, p 6585 (2021)
institution DOAJ
collection DOAJ
language EN
topic ceramic–polymer composites
intelligent materials
protective properties
rheological properties
shear thickening fluids
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
spellingShingle ceramic–polymer composites
intelligent materials
protective properties
rheological properties
shear thickening fluids
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
Radosław Żurowski
Paweł Falkowski
Justyna Zygmuntowicz
Mikołaj Szafran
Rheological and Technological Aspects in Designing the Properties of Shear Thickening Fluids
description This work focuses on shear thickening fluids (STFs) as ceramic–polymer composites with outstanding protective properties. The investigation aims to determine the influence of raw material parameters on the functional properties of STFs. The following analyses were used to characterize both the raw materials and the STFs: scanning electron microscopy, dynamic light scattering, matrix-assisted laser desorption/ionization time-of-flight, chemical sorption analysis, rheological analysis, and kinetic energy dissipation tests. It was confirmed that the morphology of the solid particles plays a key role in designing the rheological and protective properties of STFs. In the case of irregular silica, shear thickening properties can be obtained from a solid content of 12.5 vol.%. For spherical silica, the limit for achieving shear thickening behavior is 40 vol.%. The viscosity curve analysis allowed for the introduction of a new parameter defining the functional properties of STFs: the technological critical shear rate. The ability of STFs to dissipate kinetic energy was determined using a unique device that allows pure fluids to be tested without prior encapsulation. Because of this, it was possible to observe even slight differences in the protective properties between different STFs, which has not been possible so far. During tests with an energy of 50 J, the dissipation factor was over 96%.
format article
author Radosław Żurowski
Paweł Falkowski
Justyna Zygmuntowicz
Mikołaj Szafran
author_facet Radosław Żurowski
Paweł Falkowski
Justyna Zygmuntowicz
Mikołaj Szafran
author_sort Radosław Żurowski
title Rheological and Technological Aspects in Designing the Properties of Shear Thickening Fluids
title_short Rheological and Technological Aspects in Designing the Properties of Shear Thickening Fluids
title_full Rheological and Technological Aspects in Designing the Properties of Shear Thickening Fluids
title_fullStr Rheological and Technological Aspects in Designing the Properties of Shear Thickening Fluids
title_full_unstemmed Rheological and Technological Aspects in Designing the Properties of Shear Thickening Fluids
title_sort rheological and technological aspects in designing the properties of shear thickening fluids
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/8df8ad06319f49be98714590c9640d86
work_keys_str_mv AT radosławzurowski rheologicalandtechnologicalaspectsindesigningthepropertiesofshearthickeningfluids
AT pawełfalkowski rheologicalandtechnologicalaspectsindesigningthepropertiesofshearthickeningfluids
AT justynazygmuntowicz rheologicalandtechnologicalaspectsindesigningthepropertiesofshearthickeningfluids
AT mikołajszafran rheologicalandtechnologicalaspectsindesigningthepropertiesofshearthickeningfluids
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