NaAlTi3O8, A Novel Anode Material for Sodium Ion Battery
Abstract Sodium ion batteries are being considered as an alternative to lithium ion batteries in large-scale energy storage applications owing to the low cost. A novel titanate compound, NaAlTi3O8, was successfully synthesized and tested as a promising anode material for sodium ion batteries. Powder...
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2017
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oai:doaj.org-article:8dfed01217874d61bf6ae9696e6da2672021-12-02T11:50:55ZNaAlTi3O8, A Novel Anode Material for Sodium Ion Battery10.1038/s41598-017-00202-y2045-2322https://doaj.org/article/8dfed01217874d61bf6ae9696e6da2672017-03-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-00202-yhttps://doaj.org/toc/2045-2322Abstract Sodium ion batteries are being considered as an alternative to lithium ion batteries in large-scale energy storage applications owing to the low cost. A novel titanate compound, NaAlTi3O8, was successfully synthesized and tested as a promising anode material for sodium ion batteries. Powder X-ray Diffraction (XRD) and refinement were used to analyze the crystal structure. Electrochemical cycling tests under a C/10 rate between 0.01 - 2.5 V showed that ~83 mAh/g capacity could be achieved in the second cycle, with ~75% of which retained after 100 cycles, which corresponds to 0.75 Na+ insertion and extraction. The influence of synthesis conditions on electrochemical performances was investigated and discussed. NaAlTi3O8 not only presents a new anode material with low average voltage of ~0.5 V, but also provides a new type of intercalation anode with a crystal structure that differentiates from the anodes that have been reported.Xuetian MaKe AnJianming BaiHailong ChenNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-9 (2017) |
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Medicine R Science Q Xuetian Ma Ke An Jianming Bai Hailong Chen NaAlTi3O8, A Novel Anode Material for Sodium Ion Battery |
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Abstract Sodium ion batteries are being considered as an alternative to lithium ion batteries in large-scale energy storage applications owing to the low cost. A novel titanate compound, NaAlTi3O8, was successfully synthesized and tested as a promising anode material for sodium ion batteries. Powder X-ray Diffraction (XRD) and refinement were used to analyze the crystal structure. Electrochemical cycling tests under a C/10 rate between 0.01 - 2.5 V showed that ~83 mAh/g capacity could be achieved in the second cycle, with ~75% of which retained after 100 cycles, which corresponds to 0.75 Na+ insertion and extraction. The influence of synthesis conditions on electrochemical performances was investigated and discussed. NaAlTi3O8 not only presents a new anode material with low average voltage of ~0.5 V, but also provides a new type of intercalation anode with a crystal structure that differentiates from the anodes that have been reported. |
format |
article |
author |
Xuetian Ma Ke An Jianming Bai Hailong Chen |
author_facet |
Xuetian Ma Ke An Jianming Bai Hailong Chen |
author_sort |
Xuetian Ma |
title |
NaAlTi3O8, A Novel Anode Material for Sodium Ion Battery |
title_short |
NaAlTi3O8, A Novel Anode Material for Sodium Ion Battery |
title_full |
NaAlTi3O8, A Novel Anode Material for Sodium Ion Battery |
title_fullStr |
NaAlTi3O8, A Novel Anode Material for Sodium Ion Battery |
title_full_unstemmed |
NaAlTi3O8, A Novel Anode Material for Sodium Ion Battery |
title_sort |
naalti3o8, a novel anode material for sodium ion battery |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/8dfed01217874d61bf6ae9696e6da267 |
work_keys_str_mv |
AT xuetianma naalti3o8anovelanodematerialforsodiumionbattery AT kean naalti3o8anovelanodematerialforsodiumionbattery AT jianmingbai naalti3o8anovelanodematerialforsodiumionbattery AT hailongchen naalti3o8anovelanodematerialforsodiumionbattery |
_version_ |
1718395176292974592 |