Asymmetric three-component olefin dicarbofunctionalization enabled by photoredox and copper dual catalysis

Asymmetric three-component olefin dicarbofunctionalization enabled by photoredox and copper dual catalysis

Vicinal dicarbofunctionalization (DCF) reactions of alkenes have been extensively explored in ionic chemistry but the enantioselective radical mediated version of DCF remains largely unexplored. Here, the authors demonstrate a radical vicinal DCF reaction of olefins by merging of radical addition an...

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Autores principales: Peng-Zi Wang, Yuan Gao, Jun Chen, Xiao-Die Huan, Wen-Jing Xiao, Jia-Rong Chen
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/8e07c08667cc47789a6b55f4efbb3808
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spelling oai:doaj.org-article:8e07c08667cc47789a6b55f4efbb38082021-12-02T11:44:50ZAsymmetric three-component olefin dicarbofunctionalization enabled by photoredox and copper dual catalysis10.1038/s41467-021-22127-x2041-1723https://doaj.org/article/8e07c08667cc47789a6b55f4efbb38082021-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-22127-xhttps://doaj.org/toc/2041-1723Vicinal dicarbofunctionalization (DCF) reactions of alkenes have been extensively explored in ionic chemistry but the enantioselective radical mediated version of DCF remains largely unexplored. Here, the authors demonstrate a radical vicinal DCF reaction of olefins by merging of radical addition and cross-coupling using photoredox and copper dual catalysis.Peng-Zi WangYuan GaoJun ChenXiao-Die HuanWen-Jing XiaoJia-Rong ChenNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-10 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Peng-Zi Wang
Yuan Gao
Jun Chen
Xiao-Die Huan
Wen-Jing Xiao
Jia-Rong Chen
Asymmetric three-component olefin dicarbofunctionalization enabled by photoredox and copper dual catalysis
description Vicinal dicarbofunctionalization (DCF) reactions of alkenes have been extensively explored in ionic chemistry but the enantioselective radical mediated version of DCF remains largely unexplored. Here, the authors demonstrate a radical vicinal DCF reaction of olefins by merging of radical addition and cross-coupling using photoredox and copper dual catalysis.
format article
author Peng-Zi Wang
Yuan Gao
Jun Chen
Xiao-Die Huan
Wen-Jing Xiao
Jia-Rong Chen
author_facet Peng-Zi Wang
Yuan Gao
Jun Chen
Xiao-Die Huan
Wen-Jing Xiao
Jia-Rong Chen
author_sort Peng-Zi Wang
title Asymmetric three-component olefin dicarbofunctionalization enabled by photoredox and copper dual catalysis
title_short Asymmetric three-component olefin dicarbofunctionalization enabled by photoredox and copper dual catalysis
title_full Asymmetric three-component olefin dicarbofunctionalization enabled by photoredox and copper dual catalysis
title_fullStr Asymmetric three-component olefin dicarbofunctionalization enabled by photoredox and copper dual catalysis
title_full_unstemmed Asymmetric three-component olefin dicarbofunctionalization enabled by photoredox and copper dual catalysis
title_sort asymmetric three-component olefin dicarbofunctionalization enabled by photoredox and copper dual catalysis
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/8e07c08667cc47789a6b55f4efbb3808
work_keys_str_mv AT pengziwang asymmetricthreecomponentolefindicarbofunctionalizationenabledbyphotoredoxandcopperdualcatalysis
AT yuangao asymmetricthreecomponentolefindicarbofunctionalizationenabledbyphotoredoxandcopperdualcatalysis
AT junchen asymmetricthreecomponentolefindicarbofunctionalizationenabledbyphotoredoxandcopperdualcatalysis
AT xiaodiehuan asymmetricthreecomponentolefindicarbofunctionalizationenabledbyphotoredoxandcopperdualcatalysis
AT wenjingxiao asymmetricthreecomponentolefindicarbofunctionalizationenabledbyphotoredoxandcopperdualcatalysis
AT jiarongchen asymmetricthreecomponentolefindicarbofunctionalizationenabledbyphotoredoxandcopperdualcatalysis
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