Reaction selectivity of homochiral versus heterochiral intermolecular reactions of prochiral terminal alkynes on surfaces

Controlling selectivity between homochiral and heterochiral reaction pathways on surfaces is intriguing but challenging. Here, the authors demonstrate strategies in steering the reactions of prochiral terminal alkynes between the homochiral and heterochiral pathways by tuning the precursor substitue...

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Autores principales:	Tao Wang, Haifeng Lv, Jianmin Huang, Huan Shan, Lin Feng, Yahui Mao, Jinyi Wang, Wenzhao Zhang, Dong Han, Qian Xu, Pingwu Du, Aidi Zhao, Xiaojun Wu, Steven L. Tait, Junfa Zhu
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/8ed24b3268f54fc4b4b891543f4d1115
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spelling	oai:doaj.org-article:8ed24b3268f54fc4b4b891543f4d11152021-12-02T15:35:13ZReaction selectivity of homochiral versus heterochiral intermolecular reactions of prochiral terminal alkynes on surfaces10.1038/s41467-019-12102-y2041-1723https://doaj.org/article/8ed24b3268f54fc4b4b891543f4d11152019-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12102-yhttps://doaj.org/toc/2041-1723Controlling selectivity between homochiral and heterochiral reaction pathways on surfaces is intriguing but challenging. Here, the authors demonstrate strategies in steering the reactions of prochiral terminal alkynes between the homochiral and heterochiral pathways by tuning the precursor substituents and the kinetic parameters.Tao WangHaifeng LvJianmin HuangHuan ShanLin FengYahui MaoJinyi WangWenzhao ZhangDong HanQian XuPingwu DuAidi ZhaoXiaojun WuSteven L. TaitJunfa ZhuNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Tao Wang Haifeng Lv Jianmin Huang Huan Shan Lin Feng Yahui Mao Jinyi Wang Wenzhao Zhang Dong Han Qian Xu Pingwu Du Aidi Zhao Xiaojun Wu Steven L. Tait Junfa Zhu Reaction selectivity of homochiral versus heterochiral intermolecular reactions of prochiral terminal alkynes on surfaces
description	Controlling selectivity between homochiral and heterochiral reaction pathways on surfaces is intriguing but challenging. Here, the authors demonstrate strategies in steering the reactions of prochiral terminal alkynes between the homochiral and heterochiral pathways by tuning the precursor substituents and the kinetic parameters.
format	article
author	Tao Wang Haifeng Lv Jianmin Huang Huan Shan Lin Feng Yahui Mao Jinyi Wang Wenzhao Zhang Dong Han Qian Xu Pingwu Du Aidi Zhao Xiaojun Wu Steven L. Tait Junfa Zhu
author_facet	Tao Wang Haifeng Lv Jianmin Huang Huan Shan Lin Feng Yahui Mao Jinyi Wang Wenzhao Zhang Dong Han Qian Xu Pingwu Du Aidi Zhao Xiaojun Wu Steven L. Tait Junfa Zhu
author_sort	Tao Wang
title	Reaction selectivity of homochiral versus heterochiral intermolecular reactions of prochiral terminal alkynes on surfaces
title_short	Reaction selectivity of homochiral versus heterochiral intermolecular reactions of prochiral terminal alkynes on surfaces
title_full	Reaction selectivity of homochiral versus heterochiral intermolecular reactions of prochiral terminal alkynes on surfaces
title_fullStr	Reaction selectivity of homochiral versus heterochiral intermolecular reactions of prochiral terminal alkynes on surfaces
title_full_unstemmed	Reaction selectivity of homochiral versus heterochiral intermolecular reactions of prochiral terminal alkynes on surfaces
title_sort	reaction selectivity of homochiral versus heterochiral intermolecular reactions of prochiral terminal alkynes on surfaces
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/8ed24b3268f54fc4b4b891543f4d1115
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Reaction selectivity of homochiral versus heterochiral intermolecular reactions of prochiral terminal alkynes on surfaces

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