Coordination environment dependent selectivity of single-site-Cu enriched crystalline porous catalysts in CO2 reduction to CH4

Crystalline porous catalysts with single Cu sites are dedicated to exploring the dependence of CO2 electroreduction selectivity on the coordination environment of catalytic sites. The conductive MOF Cu-DBC with oxygen-coordinated Cu sites shows a high Faradaic efficiency ~80% of CO2-to-CH4.

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Autores principales: Yu Zhang, Long-Zhang Dong, Shan Li, Xin Huang, Jia-Nan Chang, Jian-Hui Wang, Jie Zhou, Shun-Li Li, Ya-Qian Lan
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/8ee2727469ef40118cad5038aa0bf742
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spelling oai:doaj.org-article:8ee2727469ef40118cad5038aa0bf7422021-11-08T11:12:38ZCoordination environment dependent selectivity of single-site-Cu enriched crystalline porous catalysts in CO2 reduction to CH410.1038/s41467-021-26724-82041-1723https://doaj.org/article/8ee2727469ef40118cad5038aa0bf7422021-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-26724-8https://doaj.org/toc/2041-1723Crystalline porous catalysts with single Cu sites are dedicated to exploring the dependence of CO2 electroreduction selectivity on the coordination environment of catalytic sites. The conductive MOF Cu-DBC with oxygen-coordinated Cu sites shows a high Faradaic efficiency ~80% of CO2-to-CH4.Yu ZhangLong-Zhang DongShan LiXin HuangJia-Nan ChangJian-Hui WangJie ZhouShun-Li LiYa-Qian LanNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Yu Zhang
Long-Zhang Dong
Shan Li
Xin Huang
Jia-Nan Chang
Jian-Hui Wang
Jie Zhou
Shun-Li Li
Ya-Qian Lan
Coordination environment dependent selectivity of single-site-Cu enriched crystalline porous catalysts in CO2 reduction to CH4
description Crystalline porous catalysts with single Cu sites are dedicated to exploring the dependence of CO2 electroreduction selectivity on the coordination environment of catalytic sites. The conductive MOF Cu-DBC with oxygen-coordinated Cu sites shows a high Faradaic efficiency ~80% of CO2-to-CH4.
format article
author Yu Zhang
Long-Zhang Dong
Shan Li
Xin Huang
Jia-Nan Chang
Jian-Hui Wang
Jie Zhou
Shun-Li Li
Ya-Qian Lan
author_facet Yu Zhang
Long-Zhang Dong
Shan Li
Xin Huang
Jia-Nan Chang
Jian-Hui Wang
Jie Zhou
Shun-Li Li
Ya-Qian Lan
author_sort Yu Zhang
title Coordination environment dependent selectivity of single-site-Cu enriched crystalline porous catalysts in CO2 reduction to CH4
title_short Coordination environment dependent selectivity of single-site-Cu enriched crystalline porous catalysts in CO2 reduction to CH4
title_full Coordination environment dependent selectivity of single-site-Cu enriched crystalline porous catalysts in CO2 reduction to CH4
title_fullStr Coordination environment dependent selectivity of single-site-Cu enriched crystalline porous catalysts in CO2 reduction to CH4
title_full_unstemmed Coordination environment dependent selectivity of single-site-Cu enriched crystalline porous catalysts in CO2 reduction to CH4
title_sort coordination environment dependent selectivity of single-site-cu enriched crystalline porous catalysts in co2 reduction to ch4
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/8ee2727469ef40118cad5038aa0bf742
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AT xinhuang coordinationenvironmentdependentselectivityofsinglesitecuenrichedcrystallineporouscatalystsinco2reductiontoch4
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