Simple pyrolysis of polystyrene into valuable chemicals

Overuse of polymer products has led to severe environmental problems, which are threatening survival of creatures on earth. It is urgent to tackle enormous polymer wastes with proper cycling methods. Pyrolysis of polymers into high-value chemicals and fuels is displaying great potential to address t...

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Autores principales: Lu Chao, Xiao Hang, Chen Xi
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Lenguaje:EN
Publicado: De Gruyter 2021
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Acceso en línea:https://doaj.org/article/8f301412a8a8470ead08e61c9b9d892d
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spelling oai:doaj.org-article:8f301412a8a8470ead08e61c9b9d892d2021-12-05T14:10:47ZSimple pyrolysis of polystyrene into valuable chemicals1618-722910.1515/epoly-2021-0037https://doaj.org/article/8f301412a8a8470ead08e61c9b9d892d2021-06-01T00:00:00Zhttps://doi.org/10.1515/epoly-2021-0037https://doaj.org/toc/1618-7229Overuse of polymer products has led to severe environmental problems, which are threatening survival of creatures on earth. It is urgent to tackle enormous polymer wastes with proper cycling methods. Pyrolysis of polymers into high-value chemicals and fuels is displaying great potential to address the white pollution issue. In this study, we focus on chemical recycling of polystyrene, an important polymer in our everyday life, into valuable chemicals through simple pyrolysis strategy under nitrogen protection. It is found that yield of liquid product from polystyrene pyrolysis achieves as high as 76.24%, and there exists single component in the liquid product, which has been identified as styrene through hydrogen nuclear magnetic resonance spectra. Moreover, we propose monomer dissociation mechanism to explain the pyrolysis process of polystyrene based on the structure of polystyrene and experimental results.Lu ChaoXiao HangChen XiDe Gruyterarticlepolystyrenepyrolysisstyrene monomerdissociation mechanismchemical recyclingPolymers and polymer manufactureTP1080-1185ENe-Polymers, Vol 21, Iss 1, Pp 428-432 (2021)
institution DOAJ
collection DOAJ
language EN
topic polystyrene
pyrolysis
styrene monomer
dissociation mechanism
chemical recycling
Polymers and polymer manufacture
TP1080-1185
spellingShingle polystyrene
pyrolysis
styrene monomer
dissociation mechanism
chemical recycling
Polymers and polymer manufacture
TP1080-1185
Lu Chao
Xiao Hang
Chen Xi
Simple pyrolysis of polystyrene into valuable chemicals
description Overuse of polymer products has led to severe environmental problems, which are threatening survival of creatures on earth. It is urgent to tackle enormous polymer wastes with proper cycling methods. Pyrolysis of polymers into high-value chemicals and fuels is displaying great potential to address the white pollution issue. In this study, we focus on chemical recycling of polystyrene, an important polymer in our everyday life, into valuable chemicals through simple pyrolysis strategy under nitrogen protection. It is found that yield of liquid product from polystyrene pyrolysis achieves as high as 76.24%, and there exists single component in the liquid product, which has been identified as styrene through hydrogen nuclear magnetic resonance spectra. Moreover, we propose monomer dissociation mechanism to explain the pyrolysis process of polystyrene based on the structure of polystyrene and experimental results.
format article
author Lu Chao
Xiao Hang
Chen Xi
author_facet Lu Chao
Xiao Hang
Chen Xi
author_sort Lu Chao
title Simple pyrolysis of polystyrene into valuable chemicals
title_short Simple pyrolysis of polystyrene into valuable chemicals
title_full Simple pyrolysis of polystyrene into valuable chemicals
title_fullStr Simple pyrolysis of polystyrene into valuable chemicals
title_full_unstemmed Simple pyrolysis of polystyrene into valuable chemicals
title_sort simple pyrolysis of polystyrene into valuable chemicals
publisher De Gruyter
publishDate 2021
url https://doaj.org/article/8f301412a8a8470ead08e61c9b9d892d
work_keys_str_mv AT luchao simplepyrolysisofpolystyreneintovaluablechemicals
AT xiaohang simplepyrolysisofpolystyreneintovaluablechemicals
AT chenxi simplepyrolysisofpolystyreneintovaluablechemicals
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