Work, Entropy Production, and Thermodynamics of Information under Protocol Constraints

In many real-world situations, there are constraints on the ways in which a physical system can be manipulated. We investigate the entropy production (EP) and extractable work involved in bringing a system from some initial distribution p to some final distribution p^{′}, given that the set of maste...

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Autores principales: Artemy Kolchinsky, David H. Wolpert
Formato: article
Lenguaje:EN
Publicado: American Physical Society 2021
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Acceso en línea:https://doaj.org/article/8f90e5c438654b2c9f5826d4c9028add
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Sumario:In many real-world situations, there are constraints on the ways in which a physical system can be manipulated. We investigate the entropy production (EP) and extractable work involved in bringing a system from some initial distribution p to some final distribution p^{′}, given that the set of master equations available to the driving protocol obeys some constraints. We first derive general bounds on EP and extractable work, as well as a decomposition of the nonequilibrium free energy into an “accessible free energy” (which can be extracted as work, given a set of constraints) and an “inaccessible free energy” (which must be dissipated as EP). In a similar vein, we consider the thermodynamics of information in the presence of constraints and decompose the information acquired in a measurement into “accessible” and “inaccessible” components. This decomposition allows us to consider the thermodynamic efficiency of different measurements of the same system, given a set of constraints. We use our framework to analyze protocols subject to symmetry, modularity, and coarse-grained constraints and consider various examples including the Szilard box, the 2D Ising model, and a multiparticle flashing ratchet.