Work, Entropy Production, and Thermodynamics of Information under Protocol Constraints
In many real-world situations, there are constraints on the ways in which a physical system can be manipulated. We investigate the entropy production (EP) and extractable work involved in bringing a system from some initial distribution p to some final distribution p^{′}, given that the set of maste...
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American Physical Society
2021
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oai:doaj.org-article:8f90e5c438654b2c9f5826d4c9028add2021-11-03T17:29:27ZWork, Entropy Production, and Thermodynamics of Information under Protocol Constraints10.1103/PhysRevX.11.0410242160-3308https://doaj.org/article/8f90e5c438654b2c9f5826d4c9028add2021-11-01T00:00:00Zhttp://doi.org/10.1103/PhysRevX.11.041024http://doi.org/10.1103/PhysRevX.11.041024https://doaj.org/toc/2160-3308In many real-world situations, there are constraints on the ways in which a physical system can be manipulated. We investigate the entropy production (EP) and extractable work involved in bringing a system from some initial distribution p to some final distribution p^{′}, given that the set of master equations available to the driving protocol obeys some constraints. We first derive general bounds on EP and extractable work, as well as a decomposition of the nonequilibrium free energy into an “accessible free energy” (which can be extracted as work, given a set of constraints) and an “inaccessible free energy” (which must be dissipated as EP). In a similar vein, we consider the thermodynamics of information in the presence of constraints and decompose the information acquired in a measurement into “accessible” and “inaccessible” components. This decomposition allows us to consider the thermodynamic efficiency of different measurements of the same system, given a set of constraints. We use our framework to analyze protocols subject to symmetry, modularity, and coarse-grained constraints and consider various examples including the Szilard box, the 2D Ising model, and a multiparticle flashing ratchet.Artemy KolchinskyDavid H. WolpertAmerican Physical SocietyarticlePhysicsQC1-999ENPhysical Review X, Vol 11, Iss 4, p 041024 (2021) |
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Physics QC1-999 Artemy Kolchinsky David H. Wolpert Work, Entropy Production, and Thermodynamics of Information under Protocol Constraints |
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In many real-world situations, there are constraints on the ways in which a physical system can be manipulated. We investigate the entropy production (EP) and extractable work involved in bringing a system from some initial distribution p to some final distribution p^{′}, given that the set of master equations available to the driving protocol obeys some constraints. We first derive general bounds on EP and extractable work, as well as a decomposition of the nonequilibrium free energy into an “accessible free energy” (which can be extracted as work, given a set of constraints) and an “inaccessible free energy” (which must be dissipated as EP). In a similar vein, we consider the thermodynamics of information in the presence of constraints and decompose the information acquired in a measurement into “accessible” and “inaccessible” components. This decomposition allows us to consider the thermodynamic efficiency of different measurements of the same system, given a set of constraints. We use our framework to analyze protocols subject to symmetry, modularity, and coarse-grained constraints and consider various examples including the Szilard box, the 2D Ising model, and a multiparticle flashing ratchet. |
format |
article |
author |
Artemy Kolchinsky David H. Wolpert |
author_facet |
Artemy Kolchinsky David H. Wolpert |
author_sort |
Artemy Kolchinsky |
title |
Work, Entropy Production, and Thermodynamics of Information under Protocol Constraints |
title_short |
Work, Entropy Production, and Thermodynamics of Information under Protocol Constraints |
title_full |
Work, Entropy Production, and Thermodynamics of Information under Protocol Constraints |
title_fullStr |
Work, Entropy Production, and Thermodynamics of Information under Protocol Constraints |
title_full_unstemmed |
Work, Entropy Production, and Thermodynamics of Information under Protocol Constraints |
title_sort |
work, entropy production, and thermodynamics of information under protocol constraints |
publisher |
American Physical Society |
publishDate |
2021 |
url |
https://doaj.org/article/8f90e5c438654b2c9f5826d4c9028add |
work_keys_str_mv |
AT artemykolchinsky workentropyproductionandthermodynamicsofinformationunderprotocolconstraints AT davidhwolpert workentropyproductionandthermodynamicsofinformationunderprotocolconstraints |
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1718445526000599040 |