Egalitarian Kinetic Models: Concepts and Results

In this paper, two main ideas of chemical kinetics are distinguished, i.e., a hierarchy and commensuration. A new class of chemical kinetic models is proposed and defined, i.e., egalitarian kinetic models (EKM). Contrary to hierarchical kinetic models (HKM), for the models of the EKM class, all kine...

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Autores principales:	Denis Constales, Gregory Yablonsky, Yiming Xi, Guy Marin
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	hierarchical kinetics egalitarian kinetics acyclic and cyclic mechanisms Technology T
Acceso en línea:	https://doaj.org/article/8ff0ff0572e7497e8fd98035015f4a9b
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spelling	oai:doaj.org-article:8ff0ff0572e7497e8fd98035015f4a9b2021-11-11T15:59:39ZEgalitarian Kinetic Models: Concepts and Results10.3390/en142172301996-1073https://doaj.org/article/8ff0ff0572e7497e8fd98035015f4a9b2021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1073/14/21/7230https://doaj.org/toc/1996-1073In this paper, two main ideas of chemical kinetics are distinguished, i.e., a hierarchy and commensuration. A new class of chemical kinetic models is proposed and defined, i.e., egalitarian kinetic models (EKM). Contrary to hierarchical kinetic models (HKM), for the models of the EKM class, all kinetic coefficients are equal. Analysis of EKM models for some complex chemical reactions is performed for sequences of irreversible reactions. Analytic expressions for acyclic and cyclic mechanisms of egalitarian kinetics are obtained. Perspectives on the application of egalitarian models for reversible reactions are discussed. All analytical results are illustrated by examples.Denis ConstalesGregory YablonskyYiming XiGuy MarinMDPI AGarticlehierarchical kineticsegalitarian kineticsacyclic and cyclic mechanismsTechnologyTENEnergies, Vol 14, Iss 7230, p 7230 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	hierarchical kinetics egalitarian kinetics acyclic and cyclic mechanisms Technology T
spellingShingle	hierarchical kinetics egalitarian kinetics acyclic and cyclic mechanisms Technology T Denis Constales Gregory Yablonsky Yiming Xi Guy Marin Egalitarian Kinetic Models: Concepts and Results
description	In this paper, two main ideas of chemical kinetics are distinguished, i.e., a hierarchy and commensuration. A new class of chemical kinetic models is proposed and defined, i.e., egalitarian kinetic models (EKM). Contrary to hierarchical kinetic models (HKM), for the models of the EKM class, all kinetic coefficients are equal. Analysis of EKM models for some complex chemical reactions is performed for sequences of irreversible reactions. Analytic expressions for acyclic and cyclic mechanisms of egalitarian kinetics are obtained. Perspectives on the application of egalitarian models for reversible reactions are discussed. All analytical results are illustrated by examples.
format	article
author	Denis Constales Gregory Yablonsky Yiming Xi Guy Marin
author_facet	Denis Constales Gregory Yablonsky Yiming Xi Guy Marin
author_sort	Denis Constales
title	Egalitarian Kinetic Models: Concepts and Results
title_short	Egalitarian Kinetic Models: Concepts and Results
title_full	Egalitarian Kinetic Models: Concepts and Results
title_fullStr	Egalitarian Kinetic Models: Concepts and Results
title_full_unstemmed	Egalitarian Kinetic Models: Concepts and Results
title_sort	egalitarian kinetic models: concepts and results
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/8ff0ff0572e7497e8fd98035015f4a9b
work_keys_str_mv	AT denisconstales egalitariankineticmodelsconceptsandresults AT gregoryyablonsky egalitariankineticmodelsconceptsandresults AT yimingxi egalitariankineticmodelsconceptsandresults AT guymarin egalitariankineticmodelsconceptsandresults
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Egalitarian Kinetic Models: Concepts and Results

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