Solar Light Photoactive Floating Polyaniline/TiO<sub>2</sub> Composites for Water Remediation
In the present study, the development of innovative polyurethane-polyaniline/TiO<sub>2</sub> modified floating materials applied in the sorption and photodegradation of rhodamine B from water matrix under solar light irradiation is reported. All the materials were fabricated with inexpen...
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MDPI AG
2021
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oai:doaj.org-article:9067c7010d764c2c9790ccd76a444e302021-11-25T18:32:15ZSolar Light Photoactive Floating Polyaniline/TiO<sub>2</sub> Composites for Water Remediation10.3390/nano111130712079-4991https://doaj.org/article/9067c7010d764c2c9790ccd76a444e302021-11-01T00:00:00Zhttps://www.mdpi.com/2079-4991/11/11/3071https://doaj.org/toc/2079-4991In the present study, the development of innovative polyurethane-polyaniline/TiO<sub>2</sub> modified floating materials applied in the sorption and photodegradation of rhodamine B from water matrix under solar light irradiation is reported. All the materials were fabricated with inexpensive and easy approaches and were properly characterized. The effect of the kind of polyaniline (PANI) dopant on the materials’ behavior was investigated, as well as the role of the conducting polymer in the pollutant abatement on the basis of its physico-chemical characteristics. Rhodamine B is removed by adsorption and/or photodegradation processes depending on the type of doping agent used for PANI protonation. The best materials were subjected to recycle tests in order to demonstrate their stability under the reaction conditions. The main transformation products formed during the photodegradation process were identified by ultraperformance liquid chromatography-mass spectrometry (UPLC/MS). The results demonstrated that photoactive floating PANI/TiO<sub>2</sub> composites are useful alternatives to common powder photocatalysts for the degradation of cationic dyes.Ermelinda FallettaAnna BruniMarta SartiranaDaria C. BoffitoGiuseppina CerratoAlessia GiordanaRidha DjellabiErfan S. KhatibiClaudia L. BianchiMDPI AGarticlefloating materialscompositespolyanilinetitaniawater remediationphotocatalysisChemistryQD1-999ENNanomaterials, Vol 11, Iss 3071, p 3071 (2021) |
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DOAJ |
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floating materials composites polyaniline titania water remediation photocatalysis Chemistry QD1-999 |
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floating materials composites polyaniline titania water remediation photocatalysis Chemistry QD1-999 Ermelinda Falletta Anna Bruni Marta Sartirana Daria C. Boffito Giuseppina Cerrato Alessia Giordana Ridha Djellabi Erfan S. Khatibi Claudia L. Bianchi Solar Light Photoactive Floating Polyaniline/TiO<sub>2</sub> Composites for Water Remediation |
description |
In the present study, the development of innovative polyurethane-polyaniline/TiO<sub>2</sub> modified floating materials applied in the sorption and photodegradation of rhodamine B from water matrix under solar light irradiation is reported. All the materials were fabricated with inexpensive and easy approaches and were properly characterized. The effect of the kind of polyaniline (PANI) dopant on the materials’ behavior was investigated, as well as the role of the conducting polymer in the pollutant abatement on the basis of its physico-chemical characteristics. Rhodamine B is removed by adsorption and/or photodegradation processes depending on the type of doping agent used for PANI protonation. The best materials were subjected to recycle tests in order to demonstrate their stability under the reaction conditions. The main transformation products formed during the photodegradation process were identified by ultraperformance liquid chromatography-mass spectrometry (UPLC/MS). The results demonstrated that photoactive floating PANI/TiO<sub>2</sub> composites are useful alternatives to common powder photocatalysts for the degradation of cationic dyes. |
format |
article |
author |
Ermelinda Falletta Anna Bruni Marta Sartirana Daria C. Boffito Giuseppina Cerrato Alessia Giordana Ridha Djellabi Erfan S. Khatibi Claudia L. Bianchi |
author_facet |
Ermelinda Falletta Anna Bruni Marta Sartirana Daria C. Boffito Giuseppina Cerrato Alessia Giordana Ridha Djellabi Erfan S. Khatibi Claudia L. Bianchi |
author_sort |
Ermelinda Falletta |
title |
Solar Light Photoactive Floating Polyaniline/TiO<sub>2</sub> Composites for Water Remediation |
title_short |
Solar Light Photoactive Floating Polyaniline/TiO<sub>2</sub> Composites for Water Remediation |
title_full |
Solar Light Photoactive Floating Polyaniline/TiO<sub>2</sub> Composites for Water Remediation |
title_fullStr |
Solar Light Photoactive Floating Polyaniline/TiO<sub>2</sub> Composites for Water Remediation |
title_full_unstemmed |
Solar Light Photoactive Floating Polyaniline/TiO<sub>2</sub> Composites for Water Remediation |
title_sort |
solar light photoactive floating polyaniline/tio<sub>2</sub> composites for water remediation |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/9067c7010d764c2c9790ccd76a444e30 |
work_keys_str_mv |
AT ermelindafalletta solarlightphotoactivefloatingpolyanilinetiosub2subcompositesforwaterremediation AT annabruni solarlightphotoactivefloatingpolyanilinetiosub2subcompositesforwaterremediation AT martasartirana solarlightphotoactivefloatingpolyanilinetiosub2subcompositesforwaterremediation AT dariacboffito solarlightphotoactivefloatingpolyanilinetiosub2subcompositesforwaterremediation AT giuseppinacerrato solarlightphotoactivefloatingpolyanilinetiosub2subcompositesforwaterremediation AT alessiagiordana solarlightphotoactivefloatingpolyanilinetiosub2subcompositesforwaterremediation AT ridhadjellabi solarlightphotoactivefloatingpolyanilinetiosub2subcompositesforwaterremediation AT erfanskhatibi solarlightphotoactivefloatingpolyanilinetiosub2subcompositesforwaterremediation AT claudialbianchi solarlightphotoactivefloatingpolyanilinetiosub2subcompositesforwaterremediation |
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1718411031937548288 |