Gum Arabic-Magnetite Nanocomposite as an Eco-Friendly Adsorbent for Removal of Lead(II) Ions from Aqueous Solutions: Equilibrium, Kinetic and Thermodynamic Studies

In this study, a gum Arabic-magnetite nanocomposite (GA/MNPs) was synthesized using the solution method. The prepared nanocomposite was characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD)...

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Autores principales: Ismat H. Ali, Mutasem Z. Bani-Fwaz, Adel A. El-Zahhar, Riadh Marzouki, Mosbah Jemmali, Sara M. Ebraheem
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Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/90a378ea33974087bb69b4ed6844f8d1
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spelling oai:doaj.org-article:90a378ea33974087bb69b4ed6844f8d12021-11-25T18:59:29ZGum Arabic-Magnetite Nanocomposite as an Eco-Friendly Adsorbent for Removal of Lead(II) Ions from Aqueous Solutions: Equilibrium, Kinetic and Thermodynamic Studies10.3390/separations81102242297-8739https://doaj.org/article/90a378ea33974087bb69b4ed6844f8d12021-11-01T00:00:00Zhttps://www.mdpi.com/2297-8739/8/11/224https://doaj.org/toc/2297-8739In this study, a gum Arabic-magnetite nanocomposite (GA/MNPs) was synthesized using the solution method. The prepared nanocomposite was characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and thermogravimetric analysis (TGA). The prepared composite was evaluated for the adsorption of lead(II) ions from aqueous solutions. The controlling factors such as pH, contact time, adsorbent dose, initial ion concentration, and temperature were investigated. The optimum adsorption conditions were found to be 0.3 g/50 mL, pH = 6.00, and contact time of 30 min. The experimental data well fitted the pseudo-second-order kinetic model and the Langmuir isotherm model. The maximum adsorption capacity was determined as 50.5 mg/g. Thermodynamic parameters were calculated postulating an endothermic and spontaneous process and a physio-sorption pathway.Ismat H. AliMutasem Z. Bani-FwazAdel A. El-ZahharRiadh MarzoukiMosbah JemmaliSara M. EbraheemMDPI AGarticleadsorptiongum Arabicmagnetitenano-compositelead(II)PhysicsQC1-999ChemistryQD1-999ENSeparations, Vol 8, Iss 224, p 224 (2021)
institution DOAJ
collection DOAJ
language EN
topic adsorption
gum Arabic
magnetite
nano-composite
lead(II)
Physics
QC1-999
Chemistry
QD1-999
spellingShingle adsorption
gum Arabic
magnetite
nano-composite
lead(II)
Physics
QC1-999
Chemistry
QD1-999
Ismat H. Ali
Mutasem Z. Bani-Fwaz
Adel A. El-Zahhar
Riadh Marzouki
Mosbah Jemmali
Sara M. Ebraheem
Gum Arabic-Magnetite Nanocomposite as an Eco-Friendly Adsorbent for Removal of Lead(II) Ions from Aqueous Solutions: Equilibrium, Kinetic and Thermodynamic Studies
description In this study, a gum Arabic-magnetite nanocomposite (GA/MNPs) was synthesized using the solution method. The prepared nanocomposite was characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and thermogravimetric analysis (TGA). The prepared composite was evaluated for the adsorption of lead(II) ions from aqueous solutions. The controlling factors such as pH, contact time, adsorbent dose, initial ion concentration, and temperature were investigated. The optimum adsorption conditions were found to be 0.3 g/50 mL, pH = 6.00, and contact time of 30 min. The experimental data well fitted the pseudo-second-order kinetic model and the Langmuir isotherm model. The maximum adsorption capacity was determined as 50.5 mg/g. Thermodynamic parameters were calculated postulating an endothermic and spontaneous process and a physio-sorption pathway.
format article
author Ismat H. Ali
Mutasem Z. Bani-Fwaz
Adel A. El-Zahhar
Riadh Marzouki
Mosbah Jemmali
Sara M. Ebraheem
author_facet Ismat H. Ali
Mutasem Z. Bani-Fwaz
Adel A. El-Zahhar
Riadh Marzouki
Mosbah Jemmali
Sara M. Ebraheem
author_sort Ismat H. Ali
title Gum Arabic-Magnetite Nanocomposite as an Eco-Friendly Adsorbent for Removal of Lead(II) Ions from Aqueous Solutions: Equilibrium, Kinetic and Thermodynamic Studies
title_short Gum Arabic-Magnetite Nanocomposite as an Eco-Friendly Adsorbent for Removal of Lead(II) Ions from Aqueous Solutions: Equilibrium, Kinetic and Thermodynamic Studies
title_full Gum Arabic-Magnetite Nanocomposite as an Eco-Friendly Adsorbent for Removal of Lead(II) Ions from Aqueous Solutions: Equilibrium, Kinetic and Thermodynamic Studies
title_fullStr Gum Arabic-Magnetite Nanocomposite as an Eco-Friendly Adsorbent for Removal of Lead(II) Ions from Aqueous Solutions: Equilibrium, Kinetic and Thermodynamic Studies
title_full_unstemmed Gum Arabic-Magnetite Nanocomposite as an Eco-Friendly Adsorbent for Removal of Lead(II) Ions from Aqueous Solutions: Equilibrium, Kinetic and Thermodynamic Studies
title_sort gum arabic-magnetite nanocomposite as an eco-friendly adsorbent for removal of lead(ii) ions from aqueous solutions: equilibrium, kinetic and thermodynamic studies
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/90a378ea33974087bb69b4ed6844f8d1
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