Borane-catalysed S–H insertion reaction of thiophenols and thiols with α-aryl-α-diazoesters
Herein, we have developed a novel B(C6F5)3-catalysed S–H bond insertion of thiophenols and thiols with α-aryl-α-diazoesters under mild conditions, furnishing various sulfides in moderate to excellent yield. This method features simple operation, mild conditions, broad substrate scope and easy scale-...
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| Main Authors: | , , , , |
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| Format: | article |
| Language: | EN |
| Published: |
KeAi Communications Co. Ltd.
2021
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| Subjects: | |
| Online Access: | https://doaj.org/article/90d579aed92f4a18a153c93583bdb5b0 |
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| Summary: | Herein, we have developed a novel B(C6F5)3-catalysed S–H bond insertion of thiophenols and thiols with α-aryl-α-diazoesters under mild conditions, furnishing various sulfides in moderate to excellent yield. This method features simple operation, mild conditions, broad substrate scope and easy scale-up, which provide an alternative approach for transition-metal catalysed reaction. |
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