Borane-catalysed S–H insertion reaction of thiophenols and thiols with α-aryl-α-diazoesters

Herein, we have developed a novel B(C6F5)3-catalysed S–H bond insertion of thiophenols and thiols with α-aryl-α-diazoesters under mild conditions, furnishing various sulfides in moderate to excellent yield. This method features simple operation, mild conditions, broad substrate scope and easy scale-...

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Autores principales:	Kexin Dong, Xun-Shen Liu, Xiaoyan Wei, Yuting Zhao, Lu Liu
Formato:	article
Lenguaje:	EN
Publicado:	KeAi Communications Co. Ltd. 2021
Materias:	Borane-catalysed Diazoester S–H insertion Thiophenols Thiols C–S bond Formation Chemical technology TP1-1185 Biochemistry QD415-436
Acceso en línea:	https://doaj.org/article/90d579aed92f4a18a153c93583bdb5b0
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spelling	oai:doaj.org-article:90d579aed92f4a18a153c93583bdb5b02021-12-02T05:03:58ZBorane-catalysed S–H insertion reaction of thiophenols and thiols with α-aryl-α-diazoesters2666-554910.1016/j.gresc.2021.10.001https://doaj.org/article/90d579aed92f4a18a153c93583bdb5b02021-11-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S266655492100082Xhttps://doaj.org/toc/2666-5549Herein, we have developed a novel B(C6F5)3-catalysed S–H bond insertion of thiophenols and thiols with α-aryl-α-diazoesters under mild conditions, furnishing various sulfides in moderate to excellent yield. This method features simple operation, mild conditions, broad substrate scope and easy scale-up, which provide an alternative approach for transition-metal catalysed reaction.Kexin DongXun-Shen LiuXiaoyan WeiYuting ZhaoLu LiuKeAi Communications Co. Ltd.articleBorane-catalysedDiazoesterS–H insertionThiophenolsThiolsC–S bond FormationChemical technologyTP1-1185BiochemistryQD415-436ENGreen Synthesis and Catalysis, Vol 2, Iss 4, Pp 385-388 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Borane-catalysed Diazoester S–H insertion Thiophenols Thiols C–S bond Formation Chemical technology TP1-1185 Biochemistry QD415-436
spellingShingle	Borane-catalysed Diazoester S–H insertion Thiophenols Thiols C–S bond Formation Chemical technology TP1-1185 Biochemistry QD415-436 Kexin Dong Xun-Shen Liu Xiaoyan Wei Yuting Zhao Lu Liu Borane-catalysed S–H insertion reaction of thiophenols and thiols with α-aryl-α-diazoesters
description	Herein, we have developed a novel B(C6F5)3-catalysed S–H bond insertion of thiophenols and thiols with α-aryl-α-diazoesters under mild conditions, furnishing various sulfides in moderate to excellent yield. This method features simple operation, mild conditions, broad substrate scope and easy scale-up, which provide an alternative approach for transition-metal catalysed reaction.
format	article
author	Kexin Dong Xun-Shen Liu Xiaoyan Wei Yuting Zhao Lu Liu
author_facet	Kexin Dong Xun-Shen Liu Xiaoyan Wei Yuting Zhao Lu Liu
author_sort	Kexin Dong
title	Borane-catalysed S–H insertion reaction of thiophenols and thiols with α-aryl-α-diazoesters
title_short	Borane-catalysed S–H insertion reaction of thiophenols and thiols with α-aryl-α-diazoesters
title_full	Borane-catalysed S–H insertion reaction of thiophenols and thiols with α-aryl-α-diazoesters
title_fullStr	Borane-catalysed S–H insertion reaction of thiophenols and thiols with α-aryl-α-diazoesters
title_full_unstemmed	Borane-catalysed S–H insertion reaction of thiophenols and thiols with α-aryl-α-diazoesters
title_sort	borane-catalysed s–h insertion reaction of thiophenols and thiols with α-aryl-α-diazoesters
publisher	KeAi Communications Co. Ltd.
publishDate	2021
url	https://doaj.org/article/90d579aed92f4a18a153c93583bdb5b0
work_keys_str_mv	AT kexindong boranecatalysedshinsertionreactionofthiophenolsandthiolswithaaryladiazoesters AT xunshenliu boranecatalysedshinsertionreactionofthiophenolsandthiolswithaaryladiazoesters AT xiaoyanwei boranecatalysedshinsertionreactionofthiophenolsandthiolswithaaryladiazoesters AT yutingzhao boranecatalysedshinsertionreactionofthiophenolsandthiolswithaaryladiazoesters AT luliu boranecatalysedshinsertionreactionofthiophenolsandthiolswithaaryladiazoesters
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Borane-catalysed S–H insertion reaction of thiophenols and thiols with α-aryl-α-diazoesters

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