Amplification of enantiomeric excess by dynamic inversion of enantiomers in deracemization of Au38 clusters
Symmetry breaking and amplification processes play a fundamental role in nature and technology. Here, the authors show that the interplay between racemization and ligand exchange leads to amplification of enantiomeric excess of intrinsically chiral metal clusters.
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| Auteurs principaux: | , , |
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| Format: | article |
| Langue: | EN |
| Publié: |
Nature Portfolio
2020
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| Sujets: | |
| Accès en ligne: | https://doaj.org/article/912f1b6a348d44e9b5cdb353e96d0eef |
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| Résumé: | Symmetry breaking and amplification processes play a fundamental role in nature and technology. Here, the authors show that the interplay between racemization and ligand exchange leads to amplification of enantiomeric excess of intrinsically chiral metal clusters. |
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